Supramolecular chiroptical switches

L Zhang, HX Wang, S Li, M Liu - Chemical Society Reviews, 2020 - pubs.rsc.org
Chiroptical switches, whose chiral optical signals such as optical rotatory dispersion (ORD),
circular dichroism (CD) and circularly polarized luminescence (CPL) are reversibly …

Circularly polarized luminescence in nanoassemblies: generation, amplification, and application

Y Sang, J Han, T Zhao, P Duan, M Liu - Advanced Materials, 2020 - Wiley Online Library
Currently, the development of circularly polarized luminescent (CPL) materials has drawn
extensive attention due to the numerous potential applications in optical data storage …

The added value of small-molecule chirality in technological applications

JR Brandt, F Salerno, MJ Fuchter - Nature Reviews Chemistry, 2017 - nature.com
Chirality is a fundamental symmetry property; chiral objects, such as chiral small molecules,
exist as a pair of non-superimposable mirror images. Although small-molecule chirality is …

Circularly polarized luminescence of agglomerate emitters

C Zhang, S Li, XY Dong, SQ Zang - Aggregate, 2021 - Wiley Online Library
Circularly polarized luminescence (CPL) originates from the chiral emissive excited states.
CPL materials have promising applications in 3D optical displays, encryptions, biological …

Helical nanostructures: chirality transfer and a photodriven transformation from superhelix to nanokebab

H Jiang, Y Jiang, J Han, L Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
Photosensitive cinnamic acid conjugated glutamides were designed to demonstrate
photocontrolled hierarchical chirality transfer and switching in self‐assembled systems. In …

Organic radicals with inversion of SOMO and HOMO energies and potential applications in optoelectronics

S Kasemthaveechok, L Abella, J Crassous… - Chemical …, 2022 - pubs.rsc.org
Organic radicals possessing an electronic configuration in which the energy of the singly
occupied molecular orbital (SOMO) is below the highest doubly occupied molecular orbital …

Benzo-extended heli (aminoborane) s: Inner rim BN-doped helical molecular carbons with remarkable chiroptical properties

Y Yu, C Wang, FF Hung, C Chen, D Pan… - Journal of the …, 2024 - ACS Publications
Atomically precise synthesis of three-dimensional boron–nitrogen (BN)-based helical
structures constitutes an undeveloped field with challenges in synthetic chemistry. Herein …

Absolute configurations of synthetic molecular scaffolds from vibrational CD spectroscopy

C Merten, TP Golub, NM Kreienborg - The Journal of organic …, 2019 - ACS Publications
Vibrational circular dichroism (VCD) spectroscopy is one of the most powerful techniques for
the determination of absolute configurations (AC), as it does not require any specific UV/vis …

Helicene-based ligands enable strong magneto-chiral dichroism in a chiral ytterbium complex

M Atzori, K Dhbaibi, H Douib, M Grasser… - Journal of the …, 2021 - ACS Publications
Here we report the first experimental observation of magneto-chiral dichroism (MChD)
detected through light absorption in an enantiopure lanthanide complex. The P and M …

Multiple Chirality Switching of a Dye‐Grafted Helical Polymer Film Driven by Acid & Base

A Shi, H Wang, G Yang, C Gu, C Xiang… - Angewandte Chemie …, 2024 - Wiley Online Library
A stimuli‐responsive multiple chirality switching material, which can regulate opposed chiral
absorption characteristics, has great application value in the fields of optical modulation …