Slow invariant manifold assessments in multi-route reaction mechanism

M Shahzad, F Sultan, M Ali, WA Khan, M Irfan - Journal of Molecular Liquids, 2019 - Elsevier
A complex chemical scheme is need to reduce their complexity without losing their key
features. A chemical reaction scheme has braked down in different available reaction routes …

[HTML][HTML] The reaction routes comparison with respect to slow invariant manifold and equilibrium points

F Sultan, M Shahzad, M Ali, WA Khan - AIP Advances, 2019 - pubs.aip.org
Mathematically, complex chemical reactions can be simplified by “model reduction,” that is,
the rigorous way of approximating and representing a complex model in simplified form …

Decoding complexity of chemical reactions

GS Yablonsky - Theoretical Foundations of Chemical Engineering, 2014 - Springer
Decoding Complexity of Chemical Reactions1 Page 1 ISSN 0040 5795, Theoretical
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …

[HTML][HTML] New patterns in steady-state chemical kinetics: intersections, coincidences, map of events (two-step mechanism)

D Branco Pinto, G Yablonsky, GB Marin, D Constales - Entropy, 2015 - mdpi.com
New patterns of steady-state chemical kinetics for continuously stirred-tank reactors (CSTR)
have been found, ie, intersections, maxima and coincidences, for two-step mechanism A↔ …

Experimental confirmation of a new invariant for a non-linear chemical reaction

B Peng, GS Yablonsky, D Constales, GB Marin… - Chemical Engineering …, 2018 - Elsevier
The first non-Onsager thermodynamic invariant for a non-linear chemical system was found
experimentally in all domains using “the dual kinetic experiment” in a batch reactor in which …

Joint kinetics: A new paradigm for chemical kinetics and chemical engineering

GS Yablonsky, D Constales, GB Marin - Current Opinion in Chemical …, 2020 - Elsevier
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …

[HTML][HTML] New invariant expressions in chemical kinetics

GS Yablonsky, D Branco, GB Marin, D Constales - Entropy, 2020 - mdpi.com
This paper presents a review of our original results obtained during the last decade. These
results have been found theoretically for classical mass-action-law models of chemical …

New invariances for chemical reactions from Scaled Incremental Conversion (SIC)

PD Branco, GS Yablonsky, GB Marin… - Chemical Engineering …, 2018 - Elsevier
For the two-step chemical reaction A⇄ B⇄ C, invariant dependences of a new type have
been found. These invariants relate concentration dependences which are started from the …

Exact autonomous invariants of nonlinear chemical reactions

NI Kol'tsov - Kinetics and Catalysis, 2020 - Springer
The exact autonomous (time-independent) kinetic invariants of nonlinear chemical reactions
occurring in open systems with the participation of an independent and any number of …

Mapping the kinetic events in a linear two-step irreversible-reversible reaction mechanism

D Branco, GS Yablonsky, GB Marin… - Chemical Engineering …, 2017 - Elsevier
Kinetic events (intersections, maxima and coincidences) are mapped in the batch reactor
(BR) and the continuously stirred-tank reactor (CSTR). The mechanism A→ B⇄ C was used …