Slow invariant manifold assessments in multi-route reaction mechanism
A complex chemical scheme is need to reduce their complexity without losing their key
features. A chemical reaction scheme has braked down in different available reaction routes …
features. A chemical reaction scheme has braked down in different available reaction routes …
[HTML][HTML] The reaction routes comparison with respect to slow invariant manifold and equilibrium points
Mathematically, complex chemical reactions can be simplified by “model reduction,” that is,
the rigorous way of approximating and representing a complex model in simplified form …
the rigorous way of approximating and representing a complex model in simplified form …
Decoding complexity of chemical reactions
GS Yablonsky - Theoretical Foundations of Chemical Engineering, 2014 - Springer
Decoding Complexity of Chemical Reactions1 Page 1 ISSN 0040 5795, Theoretical
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …
[HTML][HTML] New patterns in steady-state chemical kinetics: intersections, coincidences, map of events (two-step mechanism)
New patterns of steady-state chemical kinetics for continuously stirred-tank reactors (CSTR)
have been found, ie, intersections, maxima and coincidences, for two-step mechanism A↔ …
have been found, ie, intersections, maxima and coincidences, for two-step mechanism A↔ …
Experimental confirmation of a new invariant for a non-linear chemical reaction
The first non-Onsager thermodynamic invariant for a non-linear chemical system was found
experimentally in all domains using “the dual kinetic experiment” in a batch reactor in which …
experimentally in all domains using “the dual kinetic experiment” in a batch reactor in which …
Joint kinetics: A new paradigm for chemical kinetics and chemical engineering
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …
Its main idea is performing a battery of kinetic experiments from special initial compositions …
[HTML][HTML] New invariant expressions in chemical kinetics
This paper presents a review of our original results obtained during the last decade. These
results have been found theoretically for classical mass-action-law models of chemical …
results have been found theoretically for classical mass-action-law models of chemical …
New invariances for chemical reactions from Scaled Incremental Conversion (SIC)
For the two-step chemical reaction A⇄ B⇄ C, invariant dependences of a new type have
been found. These invariants relate concentration dependences which are started from the …
been found. These invariants relate concentration dependences which are started from the …
Exact autonomous invariants of nonlinear chemical reactions
NI Kol'tsov - Kinetics and Catalysis, 2020 - Springer
The exact autonomous (time-independent) kinetic invariants of nonlinear chemical reactions
occurring in open systems with the participation of an independent and any number of …
occurring in open systems with the participation of an independent and any number of …
Mapping the kinetic events in a linear two-step irreversible-reversible reaction mechanism
Kinetic events (intersections, maxima and coincidences) are mapped in the batch reactor
(BR) and the continuously stirred-tank reactor (CSTR). The mechanism A→ B⇄ C was used …
(BR) and the continuously stirred-tank reactor (CSTR). The mechanism A→ B⇄ C was used …