Recent advances in oxidative phenol coupling for the total synthesis of natural products

MC Carson, MC Kozlowski - Natural Product Reports, 2024 - pubs.rsc.org
Covering: 2008 to 2023 This review will describe oxidative phenol coupling as applied in the
total synthesis of natural products. This review covers catalytic and electrochemical methods …

Unraveling the structure and reactivity patterns of the indole radical cation in regioselective electrochemical oxidative annulations

X Liu, D Yang, Z Liu, Y Wang, Y Liu… - Journal of the …, 2023 - ACS Publications
Oxidation-induced strategy for inert chemical bond activation through highly active radical
cation intermediate has exhibited unique reactivity. Understanding the structure and …

The chemistry of mavacurane alkaloids: A rich source of bis-indole alkaloids

A Mauger, M Jarret, C Kouklovsky, E Poupon… - Natural Product …, 2021 - pubs.rsc.org
Covering: since early reports up to the end of 2020 This review presents a complete
coverage of the mavacuranes alkaloids since early reports till date. Mavacuranes alkaloids …

Chiral Bisphosphine-Catalyzed Asymmetric Staudinger/aza-Wittig Reaction: An Enantioselective Desymmetrizing Approach to Crinine-Type Amaryllidaceae …

H Yang, J Zhang, S Zhang, Z Xue, S Hu… - Journal of the …, 2024 - ACS Publications
An unprecedented chiral bisphosphine-catalyzed asymmetric Staudinger/aza-Wittig reaction
of 2, 2-disubstituted cyclohexane-1, 3-diones is reported, enabling the facile access of a …

Enantioselective oxidative phenol-indole [3+ 2] coupling enabled by biomimetic Mn (III)/Brønsted acid relay catalysis

Q Yu, Y Fu, J Huang, J Qin, H Zuo, Y Wu, F Zhong - ACS Catalysis, 2019 - ACS Publications
A (salen) Mn (III) complex was used as a biomimetic surrogate of the metallocofactor of
phenol-oxidizing enzymes, in combination with chiral phosphoric acid relay catalysis …

Divergent Synthesis of Isoquinolone and Isocoumarin Derivatives by the Annulation of Benzoic Acid with N-Vinyl Amide

R Sun, X Yang, Q Li, K Xu, J Tang, X Zheng… - Organic …, 2019 - ACS Publications
A simple and efficient method for the synthesis of isoquinolone and isocoumarin derivatives
is reported. The method for the first time provides a one-step divergent synthesis of important …

Recent advances in catalytic oxidative reactions of phenols and naphthalenols

MA Bashir, J Wei, H Wang, F Zhong… - Organic Chemistry …, 2022 - pubs.rsc.org
Oxidative reactions provide an effective strategy for phenol transformation via conjugated
addition, C–H functionalization, cyclization reactions, etc. It has enabled broad utilization of …

Progress in Transition‐Metal‐Catalyzed Synthesis of Benzo‐Fused Oxygen‐and Nitrogen Heterocyclic Compounds from Benzoic Acids

X Yang, R Sun - Advanced Synthesis & Catalysis, 2023 - Wiley Online Library
Transition‐metal‐catalyzed oxidative annulation reactions can be used to synthesize
various benzo‐fused oxygen‐and nitrogen‐containing heterocyclic compounds from …

Catalytic asymmetric dearomative [3+ 2] cyclisation of 1, 4‐quinone with 2, 3‐disubstituted indoles

L Zhang, J Hu, R Xu, S Pan, X Zeng… - Advanced Synthesis & …, 2019 - Wiley Online Library
A chiral phosphoric acid‐catalysed asymmetric dearomative [3+ 2] cyclisation for accessing
enantioenriched benzofuroindolines with two vicinal tetrasubstituted carbon centres from …

Bioinspired oxidative cyclization of the geissoschizine skeleton for enantioselective total synthesis of mavacuran alkaloids

M Jarret, V Turpin, A Tap, JF Gallard… - Angewandte …, 2019 - Wiley Online Library
Reported is the enantioselective total syntheses of mavacuran alkaloids,(+)‐taberdivarine
H,(+)‐16‐hydroxymethyl‐pleiocarpamine, and (+)‐16‐epi‐pleiocarpamine, and their …