[HTML][HTML] The reactivity of halides of high valent groups 5 and 6 metals with oxygen and nitrogen organic donors and the parallelism with related chemistry of main …

G Bresciani, F Marchetti, G Pampaloni - Coordination Chemistry Reviews, 2023 - Elsevier
Homoleptic halides of high-valent transition metals are acidic species possessing a strong
affinity to N-and O-donors. The formation of coordination adducts with related organic …

Decarbonylation of phenylacetic acids by high valent transition metal halides

N Bartalucci, F Marchetti, S Zacchini… - Dalton Transactions, 2019 - pubs.rsc.org
Triphenylacetic acid underwent unusual decarbonylation when allowed to react with a
series of halides of group 4–6 metals in their highest oxidation state, in dichloromethane at …

Exploiting the Potentiality of High Valent Transition Metal Halides in Organic Synthesis

N Bartalucci - 2020 - tesidottorato.depositolegale.it
Halides of group 5 and 6 transition metals in a+ 5 or+ 6 oxidation state (high valent metal
halides, HVMH) are strong Lewis acids that can also exploit oxidizing power and …