Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

The catalytic conversion of renewable feedstocks into chemicals is pursued as a means to
sustainably fulfil future societal needs. Due to the oxygen-rich nature of bio-derived …

Zeolites containing Sn, Ti, Zr, Hf, Nb, or Ta heteroatoms are versatile catalysts for the
activation and conversion of oxygenated molecules owing to the unique Lewis acid …

A new route to the synthesis of TS-1 has been developed using (NH4) 2CO3 as a
crystallization-mediating agent. In this way, the framework Ti content can be significantly …

Abstract Titanosilicate-1 (TS-1) has attracted extensive attention of researchers due to its
unique shape-selective catalytic oxidation performance and excellent hydrothermal stability …

Our density functional theory study of hydroperoxy (OOH) intermediates on various model
titanosilicalite (TS-1) Ti centers explores how microstructural aspects of Ti sites effect …

This work is intended to underline how the most-advanced experimental and theoretical
physical chemistry tools must be used synergistically to understand the reactivity of Ti …

Upon loading of aqueous hydrogen peroxide into Ti silicalite sieve and removal of the
solvent by evacuation, a thermally stable hydroperoxo species was detected by infrared …

In the last decade the appearance of progressively more sophisticated codes, together with
the increased computational capabilities, has made XANES a spectroscopic technique able …

The Sn silicate zeolite, Sn-β, has been shown to be an efficient, selective heterogeneous
catalyst for Baeyer− Villiger oxidations. Using primarily a multishell fit to extended X-ray …