Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

A molecular level understanding of template effects in ionic liquids

R Elfgen, O Holloczki, B Kirchner - Accounts of Chemical …, 2017 - ACS Publications
Conspectus The structure-directing or template effect has been invoked several times for
ionic liquids to explain the different outcome in material synthesis, namely, different scaffolds …

Ionic Liquids as homogeneous photocatalyst for CO2 reduction in protic solvents

Y Peng, KC Szeto, CC Santini, S Daniele - Chemical Engineering Journal …, 2022 - Elsevier
The study focuses on the photocatalytic reduction of CO 2 in protic solvents such as iPrOH or
H 2 O and in the presence of different imidazolium-based ionic liquids (IL). Under UV–vis …

Crystallization and glass-forming ability of ionic liquids: novel insights into their thermal behavior

AIMC Lobo Ferreira, ASMC Rodrigues… - ACS Sustainable …, 2019 - ACS Publications
This work presents an extended study of the thermal behavior of the alkyl and
dialkylpyridinium derivatives of the bis (trifluoromethylsulfonyl) imide ionic liquid series …

Solvation of alcohols in ionic liquids–understanding the effect of the anion and cation

ICM Vaz, M Bastos, CES Bernardes… - Physical Chemistry …, 2018 - pubs.rsc.org
In this work, we studied the effect of anion and cation properties on the interaction of
alcohols with ionic liquids (ILs), using propan-1-ol as a molecular probe. The enthalpies of …

Decay of hydrogen bonding in mixtures of aliphatic heptanols and bistriflimide ionic liquids

V Pokorný, V Štejfa, K Růžička… - Physical Chemistry …, 2021 - pubs.rsc.org
Hydrogen bonding in liquids of the constitution isomers of heptan-1-ol mixed with 1-alkyl-3-
methylimidazolium bis (trifluoromethylsulfonyl) imide ionic liquids (ILs),[Cnmim][NTf2], is …

Microscopic solvation environments in a prototype room-temperature ionic liquid as elucidated by resonance Raman spectroscopy of iodine and bromine

S Saha, H Okajima, O Homma, H Hamaguchi - Spectrochimica Acta Part A …, 2017 - Elsevier
Microscopic solvation environments in a prototype ionic liquid, bmimTf 2 N; 1-butyl-3-methyl-
imidazolium-bis (trifluoromethanesulfonyl) imide, have been studied with the use of halides …

Proton-coupled reduction of an iron nitrosyl porphyrin in the protic ionic liquid nanodomain

A Atifi, PJ Mak, MD Ryan - Electrochimica Acta, 2019 - Elsevier
The one-electron reduction of many molecules becomes much more favorable if combined
with proton transfers or strong hydrogen bonding. Protic room temperature ionic liquids …

NANOSTRUCTURATION EFFECT ON THE PROPERTIES OF IONIC FLUIDS

LM Santos - BOOK OF ABSTRACTS, 2022 - bibliotecadigital.ipb.pt
The nanostructuration in the ionic fluids affects the trend of properties along the series and is
dependent of the alkyl chain size, cation and anion nature. In some recent publications [1-5] …