Recent advances in the applications of mesoporous silica in heterogeneous catalysis

X Yu, CT Williams - Catalysis science & technology, 2022 - pubs.rsc.org
Mesoporous silica is a class of silica material with a large specific surface area, high specific
pore volume and meso-sized pores. These properties make mesoporous silica a good …

Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts

CM Crombie, RJ Lewis, RL Taylor, DJ Morgan… - ACS …, 2021 - ACS Publications
Bimetallic Pd-Fe catalysts supported on TiO2 are shown to be highly effective toward the
selective oxidation of benzyl alcohol to benzaldehyde via the in situ production of H2O2 from …

Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium

G Cheng, A Jentys, OY Gutiérrez, Y Liu, YH Chin… - Nature Catalysis, 2021 - nature.com
Solvents not only disperse reactants to enhance mass transport in catalytic reactions but
also alter the reaction kinetically. Here, we show that the rate of benzaldehyde …

An S-scheme NH2-MIL-101 (Fe)@ MCN/Bi2O3 heterojunction photocatalyst for the degradation of tetracycline and production of H2O2

Z Li, D Shen, X Hu, X Yang, Y Li, M Bao - Chemosphere, 2023 - Elsevier
Effective and durable photocatalysts are essential for the decomposition of persistent
contaminants and the generation of hydrogen peroxide. In this study, we successfully …

Recognition of water-induced effects toward enhanced interaction between catalyst and reactant in alcohol oxidation

Q Wei, C Yu, X Song, Y Zhong, L Ni… - Journal of the …, 2021 - ACS Publications
Pickering emulsion stabilized by solid nanoparticles provides a diverse solvent
microenvironment and enables to promote the phase transfer of reaction substrates/products …

Enhanced Fatty Acid Photodecarboxylation over Bimetallic Au–Pd Core–Shell Nanoparticles Deposited on TiO2

H Yang, L Tian, A Grirrane, A García-Baldoví, J Hu… - ACS …, 2023 - ACS Publications
Photodecarboxylation of biomass-derived fatty acids to alkanes offers significant potential to
obtain hydrocarbons and economic benefits due to the mild conditions and high activity …

Atomically decorating of MnOx on palladium nanoparticles towards selective oxidation of benzyl alcohol with high yield

J Yang, K Cao, M Gong, B Shan, R Chen - Journal of catalysis, 2020 - Elsevier
Palladium nanoparticles are effective catalysts for selective oxidation of benzyl alcohol,
which is a fundamental reaction in fine chemicals production. Herein, an atomic-scale oxide …

Constructing a photocatalyst for selective oxidation of benzyl alcohol to benzaldehyde by photo-fenton-like catalysis

C Si, X Liu, T Zhang, J Xu, J Li, J Fu, Q Han - Inorganic Chemistry, 2023 - ACS Publications
A photoactive metal–organic framework (MOF),[K (H2O)][Cu (DPNDI)][Cu (DPNDI)(CH3CN)(
H2O)][Cu1. 5 (DPNDI) 1.5 H1. 5P2W18O62]· 2H2O (Cu (Ι) W–DPNDI), was prepared by …

Microenvironment tailoring mediated oxygen-vacancy defect engineering strategy facilitating O2 and alcohol activation on HEOs with superior catalytic efficiency

J Chen, B Zhang, S Shi, Y Zhu, Y Li, X Gao, H Cao… - Applied Surface …, 2024 - Elsevier
Achieving selective oxidation of biomass-derived benzyl alcohol under a mild environment
to prepare high-value-added oxygenates is an attractive goal but remains a significant …

Atomically dispersed Feδ+ anchored on nitrogen-rich carbon for enhancing benzyl alcohol oxidation through Mott-Schottky effect

Q Wei, J Wang, W Shen - Applied Catalysis B: Environmental, 2021 - Elsevier
Active and stable supported metal catalysts, with low metal loading amount and easy access
if possible, are preferentially considered and synthesized. This study reports a novel …