Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

Development of efficient and economic water oxidation catalysts (WOCs) remains a crucial
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …

The conventional homogeneous catalysts for the enantioselective hydrogenation or transfer
hydrogenation of ketones are based on platinum metals and, in particular, ruthenium. This …

TAML activators of peroxides are iron (III) complexes. The ligation by four deprotonated
amide nitrogens in macrocyclic motifs is the signature of TAMLs where the macrocyclic …

Water splitting, leading to hydrogen and oxygen in a process that mimics natural
photosynthesis, is extremely important for devising a sustainable solar energy conversion …

Asymmetric catalysis using iron complexes – ‘ Ruthenium Lite’? - Catalysis Science &
Technology (RSC Publishing) DOI:10.1039/C1CY00390A Royal Society of Chemistry View PDF …

A new heterogeneous catalyst was developed through immobilizing iron-dipicolinamide
complex on silica particles (Fedpa@ SiO 2) for the degradation of organic pollutants in …

Exceptionally high peroxidase-like and catalase-like activities of iron (III)− TAML activators of
H2O2 (1: Tetra-Amidato-Macrocyclic-Ligand FeIII complexes [F e {1, 2− X2C6H2− 4 …

High-valent iron-oxo complexes are key intermediates in C–H functionalization reactions.
Herein, we report the generation of a (TAML) Fe-oxo species (TAML= tetraamido …

Materials have been developed that encapsulate a homogeneous catalyst and enable it to
operate as a heterogeneous catalyst in water. A hydrophobic ionic liquid within the material …