Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

Herein, we report an achiral dirhodium complex and chiral phosphoric acid cooperatively
catalyzed asymmetric three-component reaction of enynal with alcohol and imine, affording …

Visible-light-induced [1+ 5] annulation of phosphoryl diazomethylarenes and pyridinium 1, 4-
zwitterionic thiolates generates various trifunctionalized dialkyl 1-phosphoryl-1, 9a …

The past decade has witnessed tremendous developments in transition‐metal‐catalyzed C−
H bond activation and subsequent carbene migratory insertion reactions, thus assisting in …

Metal carbene is an active synthetic intermediate, which has shown versatile applications in
synthetic chemistry. Although a variety of catalytic methods have been disclosed for the …

Carbenes, recognized as potent intermediates, enable unique chemical transformations,
and organoborons are pivotal in diverse chemical applications. As a hybrid of carbene and …

Pentafluorosulfanyl chloride (SF5Cl) is the most prevalent reagent for the incorporation of
SF5 group into organic compounds. However, the preparation of SF5Cl often relies on …

This paper reports the trifunctionalization reactions of tertiary enaminones in the fashion of
selective gem-and vicinal diphosphorylation, leading to the tunable synthesis of α, α-and α …

A novel copper-catalyzed [3+ 2] cycloaddition reaction of alkynes with nitrile oxides
generated in situ from the coupling reaction of copper carbene and nitroso radical has been …