[HTML][HTML] Chalcogen bonding in coordination chemistry

KT Mahmudov, AV Gurbanov, VA Aliyeva… - Coordination Chemistry …, 2022 - Elsevier
The chalcogen bond (ChB) is defined as a noncovalent interaction between the electron
density deficient region (so-called as σ or π hole) of a covalently bonded chalcogen atom …

[HTML][HTML] Chalcogen bonding in synthesis, catalysis and design of materials

KT Mahmudov, MN Kopylovich, MFCG da Silva… - Dalton …, 2017 - pubs.rsc.org
Chalcogen bonding is a type of noncovalent interaction in which a covalently bonded
chalcogen atom (O, S, Se or Te) acts as an electrophilic species towards a nucleophilic …

[图书][B] New frontiers in organoselenium compounds

EJ Lenardão, C Santi, L Sancineto - 2018 - Springer
The book New frontiers on organoselenium compounds, by Lenardão, Santi, and Sancineto,
is destined to become an extremely useful and valuable source for students and researchers …

Reactivity of acyclic diaminocarbene ligands

MA Kinzhalov, KV Luzyanin - Coordination Chemistry Reviews, 2019 - Elsevier
Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in
organometallic chemistry, catalysis, photophysics and crystal engineering. Although the …

Dramatically Enhanced Solubility of Halide‐Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅ Complex Halogen Bonding

MA Kinzhalov, MV Kashina, AS Mikherdov… - Angewandte …, 2018 - Wiley Online Library
In the current study, we evaluated the solubility of a number of organometallic species and
showed that it is noticeably improved in diiodomethane when compared to other haloalkane …

[HTML][HTML] Hexaiododiplatinate (ii) as a useful supramolecular synthon for halogen bond involving crystal engineering

AA Eliseeva, DM Ivanov, AS Novikov, AV Rozhkov… - Dalton …, 2020 - pubs.rsc.org
Hexaiododiplatinates (II) bearing ammonium and phosphonium cations,[R4N] 2 [Pt2 (μ-I)
2I4]{R= Et (1) and n-Bu (2)} and [R3PR1] 2 [Pt2 (μ-I) 2I4]{R= n-Bu and R1= n-Bu (3); R= Ph …

Electrophilic–nucleophilic dualism of nickel (II) toward Ni··· I noncovalent interactions: Semicoordination of iodine centers via electron belt and halogen bonding via σ …

ZM Bikbaeva, DM Ivanov, AS Novikov… - Inorganic …, 2017 - ACS Publications
The nitrosoguanidinate complex [Ni {NH C (NMe2) NN (O)} 2](1) was cocrystallized with I2
and sym-trifluorotriiodobenzene (FIB) to give associates 1· 2I2 and 1· 2FIB. Structures of …

Chalcogen and Hydrogen Bonds at the Periphery of Arylhydrazone Metal Complexes

AV Gurbanov, ML Kuznetsov, G Resnati… - Crystal Growth & …, 2022 - ACS Publications
Ligands comprising an intramolecular resonance-assisted hydrogen bond (RAHB) and an
intramolecular resonance-assisted chalcogen bond (RAChB) have been used to form Cu …

[HTML][HTML] Recognition of the π-hole donor ability of iodopentafluorobenzene–a conventional σ-hole donor for crystal engineering involving halogen bonding

AA Eliseeva, DM Ivanov, AS Novikov, VY Kukushkin - CrystEngComm, 2019 - pubs.rsc.org
Iodopentafluorobenzene (IPFB or PhFI) was co-crystallized with tetra (n-butyl) ammonium
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …

A novel family of polyiodo‐bromoantimonate (III) complexes: cation‐driven self‐assembly of photoconductive metal‐polyhalide frameworks

SA Adonin, LI Udalova, PA Abramov… - … A European Journal, 2018 - Wiley Online Library
In the presence of different cations, reactions of [SbBr6] 3− and I2 result in a new family of
diverse supramolecular 1D polyiodide‐bromoantimonate networks. The coordination …