Conspectus Understanding the structural architecture of nanoparticles is essential for
investigating their fundamental properties because these materials have become more …

Atomically precise metal nanoclusters (MNCs) have gained tremendous research interest in
recent years due to their extraordinary properties. The molecular-like properties that …

The controllable packing of functional nanoparticles (NPs) into crystalline lattices is of
interest in the development of NP-based materials. Here we demonstrate that the size …

The manipulation of metal cluster enantiomers and their reconstruction remain challenging.
Here, for the first time, we report an enantiomeric pair of hydride copper clusters [Cu18H …

We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag 17, prepared from
chiral alkynyl ligands. R-Ag 17 and S-Ag 17 possess C 3 symmetry and emit near-infrared …

Activation of aryl chlorides in cross-coupling reactions is a long-standing challenge in
organic synthesis that is of great interest to industry. Ultrasmall (< 3 nm), atomically precise …

Accurate identifying and in‐depth understanding of the defect sites in a working
nanomaterial could hinge on establishing specific defect‐activity relationships. Yet …

Conceptually mimicking biomolecules' ability to construct multiple‐helical aggregates with
emergent properties and functions remains a long‐standing challenge. Here we report an …

The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

Metal nanoclusters (MNCs) are compositionally well‐defined and also structurally precise
materials with unique molecule‐like properties and discrete electronic energy levels …