Solving the discrepancy between the direct and relative-rate determinations of unimolecular reaction kinetics of dimethyl-substituted Criegee intermediate (CH 3) 2 …

J Peltola, P Seal, N Vuorio, P Heinonen… - Physical Chemistry …, 2022 - pubs.rsc.org
We have performed direct kinetic measurements of the thermal unimolecular reaction of
(CH3) 2COO in the temperature range 243–340 K and pressure range 5–350 Torr using …