Recent advances of Fe–N–C pyrolyzed catalysts for the oxygen reduction reaction

K Muñoz-Becerra, R Venegas, L Duque… - Current Opinion in …, 2020 - Elsevier
This review summarizes recent advances in the development of pyrolyzed M–N–C catalysts
for the oxygen reduction reaction, focusing on activity, stability, and the reactivity descriptors …

Comparison of the catalytic activity for O 2 reduction of Fe and Co MN4 adsorbed on graphite electrodes and on carbon nanotubes

R Venegas, FJ Recio, C Zuniga, M Viera… - Physical Chemistry …, 2017 - pubs.rsc.org
We have compared the electrocatalytic activity of several substituted and unsubstituted Co
and Fe N4-macrocyclic complexes (MN4) for the electro-reduction of oxygen with the …

[HTML][HTML] Proving ligand structure-reactivity correlation on multinuclear copper electrocatalysts supported on carbon black for the oxygen reduction reaction

R Venegas, K Muñoz-Becerra, S Juillard, L Zhang… - Electrochimica …, 2022 - Elsevier
Bioinspired transition-metal catalysts seek to mimic the specific active site of
metalloenzymes, as the multicopper oxidase, that can efficiently reduce dioxygen to water …

Probing the Fen+/Fe (n− 1)+ redox potential of Fe phthalocyanines and Fe porphyrins as a reactivity descriptor in the electrochemical oxidation of cysteamine

N Silva, S Calderón, MA Páez, MP Oyarzún… - Journal of …, 2018 - Elsevier
The M n+/M (n− 1)+ redox potential of MN4 macrocyclic molecular catalysts is a very good
reactivity descriptor for several electrochemical reactions. One important feature about this …

Theoretical and experimental reactivity predictors for the electrocatalytic activity of copper phenanthroline derivatives for the reduction of dioxygen

R Venegas, K Muñoz-Becerra, L Lemus… - The Journal of …, 2019 - ACS Publications
We have systematically studied the catalytic activity of a series of substituted
bisphenanthroline Cu complexes adsorbed on glassy carbon electrodes for the oxygen …

Modulation of the electrocatalytic activity of Fe phthalocyanine to carbon nanotubes: Electrochemistry of l-cysteine and l-cystine

N Silva, C Castro-Castillo, MP Oyarzún, S Ramírez… - Electrochimica …, 2019 - Elsevier
We have evaluated the electrocatalytic activity of hybrid electrodes containing Fe (II)
phthalocyanine and tested these electrodes for l-cysteine oxidation and l-cystine reduction …

Glycoconjugated Phthalocyanines as photosensitizers for PDT–Overcoming aggregation in solution

F Bächle, N Siemens, T Ziegler - European Journal of Organic …, 2019 - Wiley Online Library
A series of new glycoconjugated zinc (II) phthalocyanines (Pcs) was synthesized and fully
characterized. The major focus of the structural design for these new Pcs was upon the …

Mapping experimental and theoretical reactivity descriptors of fe macrocyclic complexes deposited on graphite or on multi walled carbon nanotubes for the oxidation …

RA Matute, A Toro-Labbé, MP Oyarzún, S Ramirez… - Electrochimica …, 2021 - Elsevier
We have studied the electro-oxidation of thioglycolic acid (TGA) catalyzed by iron
phthalocyanines and iron porphyrins (FeN4 complexes) deposited on ordinary pyrolytic …

Aggregation behavior in unsymmetrically substituted metal-free phthalocyanines

RZU Kobak, MU Arı, A Tekin, A Gül - Chemical Physics, 2015 - Elsevier
Phthalocyanines (Pcs) generally have a strong tendency for stacking in solution to form
dimer and high order oligomers owing to the π–π, metal–ligand coordination, hydrogen …

Electrocatalytic oxidation of 2-mercaptoethanol using modified glassy carbon electrode by MWCNT in combination with unsymmetrical manganese (II) Schiff base …

S Mohebbi, S Eslami - Materials Research Bulletin, 2015 - Elsevier
The performance of modified hybrid glassy carbon electrode with composite of carbon
nanotubes and manganese complexes for the electrocatalytic oxidation of 2 …