Polyoxometalate (POM) macrocycles have been extensively investigated due to their
potential applications in various fields, including sensing, optics, magnetism, proton …

Mechanochemistry has been established to be an environmentally-friendly way of
conducting reactions in a solvent-free manner. The development of mechanochemical …

Anion binding by receptor molecules is a central field of modern chemistry which impacts
areas of catalysis as well as biological and materials chemistry. As binding often requires …

Outside the confines and well‐established domain of organic chemistry, the systematic
building of large macromolecular arrangements based on non‐carbon elements represents …

The binding and sensing of anions is an important cross-disciplinary field, which impacts
broad areas such as biology, supramolecular chemistry and catalysis. To date, however, this …

Organic selenium-and tellurium-phosphorus compounds have found wide application as
reagents in synthetic inorganic and organic chemistry, such as oxygen/chalcogen exchange …

New HB-cyclodiphosph (V) azanes with a variety of structural modifications, eg
unsymmetrical substitution of phosphorus atoms with sulfur and oxygen atoms as well as …

We herein report the synthesis, structures, coordination ability, and mechanism of formation
of silicon analogs of crown ethers. An oligomerization of 2D2 (I)(2Dn,=(Me4Si2O) n) was …

Three-dimensional covalent connectors are valuable synthons for accessing crystalline or
amorphous networks. Currently, fused polycyclic alkanes are employed as connectors in this …

Inorganic macrocycles remain challenging synthetic targets due to the limited number of
strategies reported for their syntheses. Among these species, large fully inorganic …