The iridium‐catalysed borylation of aromatic C− H bonds has become the preferred method
for the synthesis of aromatic organoboron compounds. The reaction is highly efficient …

We report herein the iridium-catalyzed meta-selective C–H borylation of benzamides by
using a newly designed 2, 2′-bipyridine (bpy) ligand bearing an alkylaluminum …

Achieving the transition metal-catalysed pyridine C3− H alkenylation, with pyridine as the
limiting reagent, has remained a long-standing challenge. Previously, we disclosed that the …

A rhodium-catalyzed annulation between ethyl benzimidates and α-aroyl sulfur ylides was
developed, affording a series of pyrano [4, 3, 2-ij] isoquinoline derivatives in moderate to …

Over the past few decades, photocatalytic C–H functionalization reactions have received
increasing attention due to the often mild reaction conditions and complementary …

Regioselectivities in catalytic C–H borylations (CHBs) have been rationalized using
simplistic steric models and correlations with nuclear magnetic resonance (NMR) chemical …

Controlling positional selectivity represents one of the most important aspects in transition-
metal-catalyzed C–H bond functionalization. However, the conventional directing template …

The regioselective C–H activation of arenes remains one of the most promising techniques
for accessing highly important functionalized motifs. Such functionalizations can generally …

Abstract Die Ir‐katalysierte Borylierung aromatischer C‐H‐Bindungen ist heute die
bevorzugte Methode zur Synthese aromatischer Organoborverbindungen. Sie ist …

A dearomative C4-allylation of benzyl ammoniums with allyltributylstannane by a palladium
catalysis is described. A triarylphosphine-ligated palladium catalyst, which is capable of …