Click nucleophilic conjugate additions to activated alkynes: exploring thiol-yne, amino-yne, and hydroxyl-yne reactions from (bio) organic to polymer chemistry
The 1, 4-conjugate addition reaction between activated alkynes or acetylenic Michael
acceptors and nucleophiles (ie, the nucleophilic Michael reaction) is a historically useful …
acceptors and nucleophiles (ie, the nucleophilic Michael reaction) is a historically useful …
Towards full recyclability of end-of-life tires: Challenges and opportunities
MS Abbas-Abadi, M Kusenberg, HM Shirazi… - Journal of Cleaner …, 2022 - Elsevier
End-of-life tires are discarded on a daily basis but even at present limited action has been
taken towards boosting their recyclability as most of the tires are either incinerated or …
taken towards boosting their recyclability as most of the tires are either incinerated or …
Spiro-salen catalysts enable the chemical synthesis of stereoregular polyhydroxyalkanoates
Although bacterial stereoregular polyhydroxyalkanoates have attracted broad interest as
sustainable materials, it remains a long-standing challenge to chemically synthesize …
sustainable materials, it remains a long-standing challenge to chemically synthesize …
Sequence control from mixtures: switchable polymerization catalysis and future materials applications
There is an ever-increasing demand for higher-performing polymeric materials
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …
[HTML][HTML] Automated iterative Csp3–C bond formation
Fully automated synthetic chemistry would substantially change the field by providing broad
on-demand access to small molecules. However, the reactions that can be run …
on-demand access to small molecules. However, the reactions that can be run …
Biobased high-performance aromatic–aliphatic polyesters with complete recyclability
YM Tu, XM Wang, X Yang, HZ Fan… - Journal of the …, 2021 - ACS Publications
The development of high-performance recyclable polymers represents a circular plastics
economy to address the urgent issues of plastic sustainability. Herein, we design a series of …
economy to address the urgent issues of plastic sustainability. Herein, we design a series of …
Sequence-and stereo-defined macromolecules: properties and emerging functionalities
R Szweda - Progress in Polymer Science, 2023 - Elsevier
Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …
functionalities in biological systems. These functionalities depend on the macromolecular …
[HTML][HTML] Recent advances in enantioselective ring-opening polymerization and copolymerization
Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy
for manipulating polymer properties. Controlled synthetic routes to prepare degradable …
for manipulating polymer properties. Controlled synthetic routes to prepare degradable …
[HTML][HTML] Natural optical activity as the origin of the large chiroptical properties in π-conjugated polymer thin films
Polymer thin films that emit and absorb circularly polarised light have been demonstrated
with the promise of achieving important technological advances; from efficient, high …
with the promise of achieving important technological advances; from efficient, high …
Editing of polymer backbones
RAJ Ditzler, AJ King, SE Towell, M Ratushnyy… - Nature Reviews …, 2023 - nature.com
Polymers are at the epicentre of modern technological progress and the associated
environmental pollution. Considerations of both polymer functionality and lifecycle are …
environmental pollution. Considerations of both polymer functionality and lifecycle are …