Electrochemical methods for water purification, ion separations, and energy conversion

MA Alkhadra, X Su, ME Suss, H Tian, EN Guyes… - Chemical …, 2022 - ACS Publications
Agricultural development, extensive industrialization, and rapid growth of the global
population have inadvertently been accompanied by environmental pollution. Water …

Fluids and electrolytes under confinement in single-digit nanopores

NR Aluru, F Aydin, MZ Bazant, D Blankschtein… - Chemical …, 2023 - ACS Publications
Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics
and chemistry that impact the mass transport and energy efficiency in many important …

The electrochemical double layer at the graphene/aqueous electrolyte interface: what we can learn from simulations, experiments, and theory

JD Elliott, AA Papaderakis, RAW Dryfe… - Journal of Materials …, 2022 - pubs.rsc.org
The physical-chemistry of the graphene/aqueous–electrolyte interface underpins the
operational conditions of a wide range of devices. Despite its importance, this interface is …

Interfacial layering in the electric double layer of ionic liquids

JP de Souza, ZAH Goodwin, M McEldrew… - Physical Review Letters, 2020 - APS
Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly interacting
environment, leading to the formation of discrete layers of charges at interfaces and spin …

Learning the physics of pattern formation from images

H Zhao, BD Storey, RD Braatz, MZ Bazant - Physical review letters, 2020 - APS
Using a framework of partial differential equation-constrained optimization, we demonstrate
that multiple constitutive relations can be extracted simultaneously from a small set of …

Molecular mean-field theory of ionic solutions: A Poisson-Nernst-Planck-Bikerman model

JL Liu, B Eisenberg - Entropy, 2020 - mdpi.com
We have developed a molecular mean-field theory—fourth-order Poisson–Nernst–Planck–
Bikerman theory—for modeling ionic and water flows in biological ion channels by treating …

Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids

PE Brandyshev, YA Budkov - The Journal of chemical physics, 2023 - pubs.aip.org
In this paper, we present a covariant approach that utilizes Noether's second theorem to
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …

Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects

YA Budkov, AL Kolesnikov - Current Opinion in Electrochemistry, 2022 - Elsevier
In this review, we shortly summarize the basic theoretical milestones achieved in the mean-
field theory of room temperature ionic liquids on charged electrodes since the publication of …

Ion correlation-driven like-charge attraction in multivalent salt solutions

NR Agrawal, R Kaur, C Carraro, R Wang - The Journal of Chemical …, 2023 - pubs.aip.org
The electrostatic double layer force is key to determining the stability and self-assembly of
charged colloids and many other soft matter systems. Fully understanding the attractive force …

Orientational ordering in nano-confined polar liquids

K Pivnic, JP de Souza, AA Kornyshev, M Urbakh… - Nano Letters, 2023 - ACS Publications
Water and other polar liquids exhibit nanoscale structuring near charged interfaces. When a
polar liquid is confined between two charged surfaces, the interfacial solvent layers begin to …