Electrochemical methods for water purification, ion separations, and energy conversion
Agricultural development, extensive industrialization, and rapid growth of the global
population have inadvertently been accompanied by environmental pollution. Water …
population have inadvertently been accompanied by environmental pollution. Water …
Fluids and electrolytes under confinement in single-digit nanopores
Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics
and chemistry that impact the mass transport and energy efficiency in many important …
and chemistry that impact the mass transport and energy efficiency in many important …
The electrochemical double layer at the graphene/aqueous electrolyte interface: what we can learn from simulations, experiments, and theory
The physical-chemistry of the graphene/aqueous–electrolyte interface underpins the
operational conditions of a wide range of devices. Despite its importance, this interface is …
operational conditions of a wide range of devices. Despite its importance, this interface is …
Interfacial layering in the electric double layer of ionic liquids
Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly interacting
environment, leading to the formation of discrete layers of charges at interfaces and spin …
environment, leading to the formation of discrete layers of charges at interfaces and spin …
Learning the physics of pattern formation from images
Using a framework of partial differential equation-constrained optimization, we demonstrate
that multiple constitutive relations can be extracted simultaneously from a small set of …
that multiple constitutive relations can be extracted simultaneously from a small set of …
Molecular mean-field theory of ionic solutions: A Poisson-Nernst-Planck-Bikerman model
JL Liu, B Eisenberg - Entropy, 2020 - mdpi.com
We have developed a molecular mean-field theory—fourth-order Poisson–Nernst–Planck–
Bikerman theory—for modeling ionic and water flows in biological ion channels by treating …
Bikerman theory—for modeling ionic and water flows in biological ion channels by treating …
Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids
PE Brandyshev, YA Budkov - The Journal of chemical physics, 2023 - pubs.aip.org
In this paper, we present a covariant approach that utilizes Noether's second theorem to
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …
Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects
YA Budkov, AL Kolesnikov - Current Opinion in Electrochemistry, 2022 - Elsevier
In this review, we shortly summarize the basic theoretical milestones achieved in the mean-
field theory of room temperature ionic liquids on charged electrodes since the publication of …
field theory of room temperature ionic liquids on charged electrodes since the publication of …
Ion correlation-driven like-charge attraction in multivalent salt solutions
The electrostatic double layer force is key to determining the stability and self-assembly of
charged colloids and many other soft matter systems. Fully understanding the attractive force …
charged colloids and many other soft matter systems. Fully understanding the attractive force …
Orientational ordering in nano-confined polar liquids
K Pivnic, JP de Souza, AA Kornyshev, M Urbakh… - Nano Letters, 2023 - ACS Publications
Water and other polar liquids exhibit nanoscale structuring near charged interfaces. When a
polar liquid is confined between two charged surfaces, the interfacial solvent layers begin to …
polar liquid is confined between two charged surfaces, the interfacial solvent layers begin to …