Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Organoselenium compounds: Chemistry and applications in organic synthesis

JM Sonego, SI De Diego, SH Szajnman… - … A European Journal, 2023 - Wiley Online Library
Selenium, originally described as a toxin, turns out to be a crucial trace element for life that
appears as selenocysteine and its dimer, selenocystine. From the point of view of drug …

[图书][B] Organoselenium chemistry

T Wirth - 2018 - orca.cardiff.ac.uk
Organoselenium chemistry has been established as a valuable research area in synthetic
and medicinal chemistry. After the discovery of the selenoxide elimination reaction in the …

Electrochemical Mn-promoted radical selenylation of boronic acids with diselenide reagents

Z Chen, Y Wang, C Hu, D Wang, P Lei, H Yi… - Organic …, 2022 - ACS Publications
A powerful and environmentally friendly electrochemical manganese-promoted free radical
selenylation reaction between boronic acids and diselenide reagents was established. This …

Rise of diselenides: Recent advances in the synthesis of heteroarylselenides

A Ivanova, P Arsenyan - Coordination Chemistry Reviews, 2018 - Elsevier
Diselenides are valuable reactants in organoselenium chemistry because Sesingle bondSe
bond can be easily converted into different reactive species, such as electrophiles (RSe+) …

Cu-catalysed Chan–Lam synthesis of unsymmetrical aryl chalcogenides under aqueous micellar conditions

N Sun, K Zheng, M Zhang, G Zheng, L Jin, B Hu… - Green …, 2023 - pubs.rsc.org
A mild Cu-catalysed Chan–Lam protocol has been developed for the synthesis of
unsymmetrical aryl chalcogenides, including selenides and sulfides, in an aqueous micellar …

Enhancing multi-resonance thermally activated delayed fluorescence emission via through-space heavy-atom effect

Q Zheng, YK Qu, P Zuo, HT Yuan, YJ Yang, YC Qiu… - Chem, 2024 - cell.com
Recent research has focused on the heavy-atom effect in organic luminescent materials,
especially in multi-resonance thermally activated delayed fluorescence (MR-TADF) emitters …

Metal-free synthesis of unsymmetrical organoselenides and selenoglycosides

Y Guan, SD Townsend - Organic letters, 2017 - ACS Publications
A one-pot, metal-free procedure has been developed to synthesize unsymmetrical
organoselenides. In the first step of the reaction, arylation of potassium selenocyanate …

Copper-catalyzed 8-aminoquinoline assisted aryl chalcogenation of ferroceneamide with aryl disulfides, diselenides, and ditellurides

M Sattar, M Shareef, K Patidar… - The Journal of Organic …, 2018 - ACS Publications
A synthetic method has been developed for the synthesis of unsymmetrical ferrocene aryl
chalcogenides by C–H activation of ferroceneamide using 8-aminoquinoline as a directing …

Organoboron compounds as versatile reagents in the transition metal-catalyzed C–S, C–Se and C–Te bond formation

AM Barcellos, M Sacramento, GP da Costa… - Coordination Chemistry …, 2021 - Elsevier
Organochalcogen compounds present synthetic and biological applications of extreme
relevance. The coupling reaction between boronic acids, borate anions or boronic esters …