Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Organic photocatalysts are emerging as viable and more sustainable tools than metal
complexes. Recently, the field of organo‐photocatalysis has experienced an explosion in …

Six-membered N-containing heterocycles, such as 2-piperidinone derivatives, with diverse
substitution patterns are widespread in natural products, drug molecules and serve as key …

Synthetic chemists have long focused on selective C (sp 3)–N bond-forming approaches in
response to the high value of this motif in natural products, pharmaceutical agents and …

The azido group is found in large numbers of natural products, drugs, biochemicals and
materials and to date, many elegant and useful methods for the synthesis of organic azides …

By utilizing an underexplored reactivity mode of N-aminopyridinium ylides, we developed
the visible-light-induced ortho-selective aminopyridylation of alkenes via radical-mediated 1 …

Direct and selective synthesis of primary amines from easily available precursors is
attractive yet challenging. Herein, we report the rapid synthesis of primary amines from …

Herein we report a practical protocol for the visible-light-induced regiodivergent radical
hydropyridylation of unactivated alkenes using pyridinium salts. This approach provides a …

Alkyl enol ethers (AEE) are versatile synthetic intermediates with a unique reactivity pattern.
This review article summarizes the synthesis of AEE as well as its reactivity and how enol …

The complexity of molecules with biological and therapeutic interests is still growing and still
creating continuous challenges that are faced with the development of the synthesis …