Delocalized excitons in natural light-harvesting complexes

SJ Jang, B Mennucci - Reviews of Modern Physics, 2018 - APS
Natural organisms such as photosynthetic bacteria, algae, and plants employ complex
molecular machinery to convert solar energy into biochemical fuel. An important common …

18 Bacteriochlorophyll Fluorescence as Processes in Photosynthetic Bacteria

P Maróti - chemistry, 2024 - api.taylorfrancis.com
18.1 INTRODUCTION property can be utilized if the bacteria are taken as models The
essential processes of photophysics, biochemistry, of the more advanced oxygenic systems …

Coherent exciton delocalization in a two-state DNA-templated dye aggregate system

BL Cannon, DL Kellis, LK Patten… - The Journal of …, 2017 - ACS Publications
Coherent exciton delocalization in dye aggregate systems gives rise to a variety of intriguing
optical phenomena, including J-and H-aggregate behavior and Davydov splitting. Systems …

Large Davydov splitting and strong fluorescence suppression: an investigation of exciton delocalization in DNA-templated Holliday junction dye aggregates

BL Cannon, LK Patten, DL Kellis… - The Journal of …, 2018 - ACS Publications
Exciton delocalization in dye aggregate systems is a phenomenon that is revealed by
spectral features, such as Davydov splitting, J-and H-aggregate behavior, and fluorescence …

A quantum chemical interpretation of two-dimensional electronic spectroscopy of light-harvesting complexes

F Segatta, L Cupellini, S Jurinovich… - Journal of the …, 2017 - ACS Publications
Nonlinear electronic spectroscopies represent one of the most powerful techniques to study
complex multichromophoric architectures. For these systems, in fact, linear spectra are too …

Benchmark and performance of long-range corrected time-dependent density functional tight binding (LC-TD-DFTB) on rhodopsins and light-harvesting complexes

BM Bold, M Sokolov, S Maity, M Wanko… - Physical Chemistry …, 2020 - pubs.rsc.org
The chromophores of rhodopsins (Rh) and light-harvesting (LH) complexes still represent a
major challenge for a quantum chemical description due to their size and complex electronic …

The role of charge-transfer states in the spectral tuning of antenna complexes of purple bacteria

M Nottoli, S Jurinovich, L Cupellini, AT Gardiner… - Photosynthesis …, 2018 - Springer
The LH2 antenna complexes of purple bacteria occur, depending on light conditions, in
various different spectroscopic forms, with a similar structure but different absorption spectra …

Before Förster. Initial excitation in photosynthetic light harvesting

KJ Karki, J Chen, A Sakurai, Q Shi, AT Gardiner… - Chemical …, 2019 - pubs.rsc.org
Electronic 2D spectroscopy allows nontrivial quantum effects to be explored in
unprecedented detail. Here, we apply recently developed fluorescence detected coherent …

An Ab Initio Description of the Excitonic Properties of LH2 and Their Temperature Dependence

L Cupellini, S Jurinovich, M Campetella… - The Journal of …, 2016 - ACS Publications
The spectroscopic properties of light-harvesting (LH) antennae in photosyntehtic organisms
represent a fingerprint that is unique for each specific pigment–protein complex. Because of …

Substituent effects on the solubility and electronic properties of the cyanine dye Cy5: Density functional and time-dependent density functional theory calculations

A Biaggne, WB Knowlton, B Yurke, J Lee, L Li - Molecules, 2021 - mdpi.com
The aggregation ability and exciton dynamics of dyes are largely affected by properties of
the dye monomers. To facilitate aggregation and improve excitonic function, dyes can be …