[HTML][HTML] Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool

MMM Hassan, S Guria, S Dey, J Das… - Science …, 2023 - science.org
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

[HTML][HTML] Synthesis of planar chiral ferrocenes via enantioselective remote C–H activation

L Zhou, HG Cheng, L Li, K Wu, J Hou, C Jiao… - Nature Chemistry, 2023 - nature.com
Planar chiral ferrocenes are widely studied structures in asymmetric catalysis, materials
science and medicinal chemistry. Although synthetic methods for 1, 2-disubstituted planar …

Remote steric control for undirected meta-selective C–H activation of arenes

B Ramadoss, Y Jin, S Asako, L Ilies - Science, 2022 - science.org
Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …

The emergence of the C–H functionalization strategy in medicinal chemistry and drug discovery

R Jana, HM Begam, E Dinda - Chemical Communications, 2021 - pubs.rsc.org
Owing to the market competitiveness and urgent societal need, an optimum speed of drug
discovery is an important criterion for successful implementation. Despite the rapid ascent of …

A tautomerized ligand enabled meta selective C–H borylation of phenol

S Guria, MMM Hassan, J Ma, S Dey, Y Liang… - Nature …, 2023 - nature.com
Remote meta selective C–H functionalization of aromatic compounds remains a challenging
problem in chemical synthesis. Here, we report an iridium catalyst bearing a bidentate …

[HTML][HTML] Ir-catalyzed proximal and distal C–H borylation of arenes

C Haldar, ME Hoque, J Chaturvedi… - Chemical …, 2021 - pubs.rsc.org
Over the past two decades, the C–H bond activation and functionalization reaction has been
known as a prevailing method for the construction of carbon–carbon and carbon …

Control of Selectivity in Homogeneous Catalysis through Noncovalent Interactions

KT Mahmudov, AJL Pombeiro - Chemistry–A European …, 2023 - Wiley Online Library
Abstract The regio‐, site‐, stereo‐or chemoselective homogeneous catalytic transformations
are extremely important for the growth/success of the current chemical industry. Based on …

Catalyst-Free C(sp2)-H Borylation through Aryl Radical Generation from Thiophenium Salts via Electron Donor–Acceptor Complex Formation

B Li, K Wang, H Yue, A Drichel, J Lin, Z Su… - Organic …, 2022 - ACS Publications
Aryl borates lie at the heart of carbon–carbon bond couplings, and they are widely applied to
the synthesis of functional materials, pharmaceutical compounds, and natural products …

Transient directing groups in metal− organic cooperative catalysis

C Jacob, BUW Maes, G Evano - Chemistry–A European …, 2021 - Wiley Online Library
The direct functionalization of C− H bonds is among the most fundamental chemical
transformations in organic synthesis. However, when the innate reactivity of the substrate …