[HTML][HTML] Metal-catalysed C–H bond activation and borylation
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …
received a remarkable level of attention as a popular reaction in the synthesis of …
Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool
MMM Hassan, S Guria, S Dey, J Das… - Science …, 2023 - science.org
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …
method that offers versatile synthetic transformation from organoboron compounds to …
[HTML][HTML] Synthesis of planar chiral ferrocenes via enantioselective remote C–H activation
L Zhou, HG Cheng, L Li, K Wu, J Hou, C Jiao… - Nature Chemistry, 2023 - nature.com
Planar chiral ferrocenes are widely studied structures in asymmetric catalysis, materials
science and medicinal chemistry. Although synthetic methods for 1, 2-disubstituted planar …
science and medicinal chemistry. Although synthetic methods for 1, 2-disubstituted planar …
Remote steric control for undirected meta-selective C–H activation of arenes
Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …
The emergence of the C–H functionalization strategy in medicinal chemistry and drug discovery
R Jana, HM Begam, E Dinda - Chemical Communications, 2021 - pubs.rsc.org
Owing to the market competitiveness and urgent societal need, an optimum speed of drug
discovery is an important criterion for successful implementation. Despite the rapid ascent of …
discovery is an important criterion for successful implementation. Despite the rapid ascent of …
A tautomerized ligand enabled meta selective C–H borylation of phenol
S Guria, MMM Hassan, J Ma, S Dey, Y Liang… - Nature …, 2023 - nature.com
Remote meta selective C–H functionalization of aromatic compounds remains a challenging
problem in chemical synthesis. Here, we report an iridium catalyst bearing a bidentate …
problem in chemical synthesis. Here, we report an iridium catalyst bearing a bidentate …
[HTML][HTML] Ir-catalyzed proximal and distal C–H borylation of arenes
Over the past two decades, the C–H bond activation and functionalization reaction has been
known as a prevailing method for the construction of carbon–carbon and carbon …
known as a prevailing method for the construction of carbon–carbon and carbon …
Control of Selectivity in Homogeneous Catalysis through Noncovalent Interactions
KT Mahmudov, AJL Pombeiro - Chemistry–A European …, 2023 - Wiley Online Library
Abstract The regio‐, site‐, stereo‐or chemoselective homogeneous catalytic transformations
are extremely important for the growth/success of the current chemical industry. Based on …
are extremely important for the growth/success of the current chemical industry. Based on …
Catalyst-Free C(sp2)-H Borylation through Aryl Radical Generation from Thiophenium Salts via Electron Donor–Acceptor Complex Formation
Aryl borates lie at the heart of carbon–carbon bond couplings, and they are widely applied to
the synthesis of functional materials, pharmaceutical compounds, and natural products …
the synthesis of functional materials, pharmaceutical compounds, and natural products …
Transient directing groups in metal− organic cooperative catalysis
The direct functionalization of C− H bonds is among the most fundamental chemical
transformations in organic synthesis. However, when the innate reactivity of the substrate …
transformations in organic synthesis. However, when the innate reactivity of the substrate …