MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Using nature's blueprint to expand catalysis with Earth-abundant metals
BACKGROUND Catalysis has had a transformative impact on society, playing a crucial role
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …
Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
[HTML][HTML] Core-shell inorganic NPs@ MOF nanostructures for targeted drug delivery and multimodal imaging-guided combination tumor treatment
It is well known that metal-organic-framework (MOF) nanostructures have unique
characteristics such as high porosity, large surface areas, and adjustable biofunctionalities …
characteristics such as high porosity, large surface areas, and adjustable biofunctionalities …
Amino acid‐functionalized metal‐organic frameworks for asymmetric base–metal catalysis
We report a strategy to develop heterogeneous single‐site enantioselective catalysts based
on naturally occurring amino acids and earth‐abundant metals for eco‐friendly asymmetric …
on naturally occurring amino acids and earth‐abundant metals for eco‐friendly asymmetric …
Electron transfer in the confined environments of metal–organic coordination supramolecular systems
Y Jin, Q Zhang, Y Zhang, C Duan - Chemical Society Reviews, 2020 - pubs.rsc.org
The incorporation of electron transfer pairs in both ground and excited states (including
electron transfer pairs in excited states and hydrogen or oxygen transfer pairs in ground …
electron transfer pairs in excited states and hydrogen or oxygen transfer pairs in ground …
Bioinspired Cu (II) Defect Sites in ZIF-8 for Selective Methane Oxidation
Y Yang, S Kanchanakungwankul… - Journal of the …, 2023 - ACS Publications
Activating the C–H bonds of alkanes without further oxidation to more thermodynamically
stable products, CO and CO2, is a long-sought goal of catalytic chemistry. Inspired by the …
stable products, CO and CO2, is a long-sought goal of catalytic chemistry. Inspired by the …
Chiral iron (II)-catalysts within valinol-grafted metal–organic frameworks for enantioselective reduction of ketones
The development of highly efficient and enantioselective heterogeneous catalysts based on
earth-abundant elements and inexpensive chiral ligands is essential for environment …
earth-abundant elements and inexpensive chiral ligands is essential for environment …
Low‐Valent Metals in Metal‐Organic Frameworks Via Post‐Synthetic Modification
Metal‐organic frameworks (MOFs) provide uniquely tunable, periodic platforms for site‐
isolation of reactive low‐valent metal complexes of relevance in modern catalysis …
isolation of reactive low‐valent metal complexes of relevance in modern catalysis …