Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
Further developments and applications of oxazoline-containing ligands in asymmetric catalysis
The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …
Rational design of bioinspired catalysts for selective oxidations
Recognizing Nature's unique ability to perform challenging oxygenation reactions with
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …
Redox-active ligands in catalysis
OR Luca, RH Crabtree - Chemical Society Reviews, 2013 - pubs.rsc.org
Redox-active ligands in catalysis - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C2CS35228A
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039/C2CS35228A …
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039/C2CS35228A …
Chiral iron catalysts for asymmetric synthesis
K Gopalaiah - Chemical Reviews, 2013 - ACS Publications
Over the past few decades, asymmetric metal catalysis has become a major area in organic
chemistry. 1 This allows efficient access to a variety of important enantiomerically enriched …
chemistry. 1 This allows efficient access to a variety of important enantiomerically enriched …
Artificial nonheme iron and manganese oxygenases for enantioselective olefin epoxidation and alkane hydroxylation reactions
J Chen, Z Jiang, S Fukuzumi, W Nam… - Coordination Chemistry …, 2020 - Elsevier
The development of sustainable enantioselective olefin epoxidation and alkane oxidation
reactions under environmentally friendly conditions is an ultimate goal that has long been …
reactions under environmentally friendly conditions is an ultimate goal that has long been …
Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts
A non-heme iron complex that catalyzes highly enantioselective epoxidation of olefins with
H2O2 is described. Improvement of enantiomeric excesses is attained by the use of catalytic …
H2O2 is described. Improvement of enantiomeric excesses is attained by the use of catalytic …
Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes
KP Bryliakov, EP Talsi - Coordination Chemistry Reviews, 2014 - Elsevier
In the last two decades, considerable efforts were invested in the search for synthetic iron
and manganese catalysts with nonporphyrinic ligands, mimicking metalloenzymes in the …
and manganese catalysts with nonporphyrinic ligands, mimicking metalloenzymes in the …
Ligand-based redox: catalytic applications and mechanistic aspects
For the last few decades, coordination chemists have seen many ligands whose role
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …
Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives
Iron coordination complexes with nitrogen and oxygen donor ligands have long since been
known to react with peroxides producing powerful oxidizing species. These compounds can …
known to react with peroxides producing powerful oxidizing species. These compounds can …