Electron transfer triggered sulfoxide isomerization in ruthenium and osmium complexes

JJ Rack - Coordination Chemistry Reviews, 2009 - Elsevier
The background and achievements in the growing field of electron-transfer triggered
sulfoxide isomerizations is reviewed. Starting with the original electrochemical investigations …

[HTML][HTML] Phototriggered structures: Latest advances in biomedical applications

M Shamsipur, A Ghavidast, A Pashabadi - Acta Pharmaceutica Sinica B, 2023 - Elsevier
Non-invasive control of the drug molecules accessibility is a key issue in improving
diagnostic and therapeutic procedures. Some studies have explored the spatiotemporal …

Dual Photoreactive Ternary Ruthenium (II) Terpyridyl Complexes: A Comparative Study on Visible-Light-Induced Single-Step Dissociation of Bidentate Ligands and …

P Chatterjee, R Mishra, S Chawla, AK Sonkar… - Inorganic …, 2024 - ACS Publications
The versatile and tunable ligand-exchange dynamics in ruthenium (II)-polypyridyl
complexes imposed by the modulation of the steric and electronic effects of the coordinated …

Excited state distortion in photochromic ruthenium sulfoxide complexes

BA McClure, ER Abrams, JJ Rack - Journal of the American …, 2010 - ACS Publications
A series of photochromic ruthenium sulfoxide complexes of the form [Ru (bpy) 2 (OSOR)]+,
where bpy is 2, 2′-bipyridine and OSOR is 2-(benzylsulfinyl) benzoate (OSOBn), 2 …

[PDF][PDF] Two-color reversible switching in a photochromic ruthenium sulfoxide complex

BA McClure, JJ Rack - Angew. Chem., Int. Ed, 2009 - academia.edu
Reversible, external triggering of molecules between two ground states is central to the
operation of modern molecular machines.[1–3] A desirable trigger is light, as it provides an …

Photoinduced and Thermal Linkage Isomerizations of an Organometallic Ionic Liquid Containing a Half-Sandwich Ruthenium Thiocyanate Complex

T Mochida, S Maekawa, R Sumitani - Inorganic Chemistry, 2021 - ACS Publications
Metal complexes with thiocyanate (SCN–) ligands typically exhibit S-or N-coordinated
linkage isomers. In this study, to explore ionic liquids that exhibit stimuli-responsiveness …

Oxidant-free synthesis of benzimidazoles from alcohols and aromatic diamines catalysed by new Ru (II)-PNS (O) pincer complexes

Q Luo, Z Dai, H Cong, R Li, T Peng, J Zhang - Dalton Transactions, 2017 - pubs.rsc.org
Benzimidazoles are chemically and pharmaceutically important, and an environmentally
benign synthetic method based on acceptorless dehydrogenative condensation of primary …

Adiabatic versus nonadiabatic photoisomerization in photochromic ruthenium sulfoxide complexes: a mechanistic picture from density functional theory calculations.

AJ Göttle, IM Dixon, F Alary, JL Heully… - Journal of the …, 2011 - ACS Publications
Polypyridine ruthenium sulfoxide complexes are intriguing compounds which can display
both photochromic and electrochromic properties. These properties are based on the Ru …

Bilability is defined when one electron is used to switch between concerted and stepwise pathways in Cu (I)-based bistable [2/3] pseudorotaxanes

AI Share, K Parimal, AH Flood - Journal of the American Chemical …, 2010 - ACS Publications
Supramolecular switches operate as simple machines by using a stimulus to turn stations off
and on, generating thermodynamic differences that define bistability and enable motion …

Photochromic ruthenium sulfoxide complexes: evidence for isomerization through a conical intersection

BA McClure, NV Mockus, DP Butcher Jr… - Inorganic …, 2009 - ACS Publications
The complexes [Ru (bpy) 2 (OS)](PF6) and [Ru (bpy) 2 (OSO)](PF6), where bpy is 2, 2′-
bipyridine, OS is 2-methylthiobenzoate, and OSO is 2-methylsulfinylbenzoate, have been …