Metal–organic framework magnets

AE Thorarinsdottir, TD Harris - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Chemically diverse and multifunctional hybrid organic–inorganic perovskites

W Li, Z Wang, F Deschler, S Gao, RH Friend… - Nature Reviews …, 2017 - nature.com
Hybrid organic–inorganic perovskites (HOIPs) can have a diverse range of compositions
including halides, azides, formates, dicyanamides, cyanides and dicyanometallates. These …

Magnetic Ordering-Induced Multiferroic Behavior in [CH3NH3][Co(HCOO)3] Metal–Organic Framework

LC Gomez-Aguirre, B Pato-Doldán, J Mira… - Journal of the …, 2016 - ACS Publications
We present the first example of magnetic ordering-induced multiferroic behavior in a metal–
organic framework magnet. This compound is [CH3NH3][Co (HCOO) 3] with a perovskite …

Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework

Y Tian, A Stroppa, Y Chai, L Yan, S Wang, P Barone… - Scientific reports, 2014 - nature.com
The coexistence of both electric and magnetic orders in some metal-organic frameworks
(MOFs) has yielded a new class of multiferroics beyond inorganic materials. However, the …

Phase transitions and coexistence of magnetic and electric orders in the methylhydrazinium metal formate frameworks

M Mączka, A Gagor, M Ptak, W Paraguassu… - Chemistry of …, 2017 - ACS Publications
We report the synthesis of four perovskite-type metal formate frameworks,[CH3NH2NH2][M
(HCOO) 3](MHyM) with M= Mn, Mg, Fe, and Zn. These compounds exhibit two structural …

Observation of magnetodielectric effect in a dysprosium-based single-molecule magnet

YX Wang, Y Ma, Y Chai, W Shi, Y Sun… - Journal of the American …, 2018 - ACS Publications
Materials that possess coupled magnetic and electric properties are of significant interest
because of their potential use in next-generation magnetoelectric devices such as digital …

Observation of resonant quantum magnetoelectric effect in a multiferroic metal–organic framework

Y Tian, S Shen, J Cong, L Yan, S Wang… - Journal of the American …, 2016 - ACS Publications
A resonant quantum magnetoelectric coupling effect has been demonstrated in the
multiferroic metal–organic framework of [(CH3) 2NH2] Fe (HCOO) 3. This material shows a …

Optoelectronic duple bistable switches: A bulk molecular single crystal and unidirectional ultraflexible thin film based on imidazolium fluorochromate

WY Zhang, Q Ye, DW Fu… - Advanced Functional …, 2017 - Wiley Online Library
Optical‐electrical duple bistable switches are those that enable simultaneous conversion of
both optical and electrical signals in one device to realize seamless integration. Herein …

Room-Temperature Polar Order in [NH4][Cd(HCOO)3] - A Hybrid Inorganic–Organic Compound with a Unique Perovskite Architecture

LC Gómez-Aguirre, B Pato-Doldán, A Stroppa… - Inorganic …, 2015 - ACS Publications
We report on the hybrid inorganic–organic ammonium compound [NH4][Cd (HCOO) 3],
which displays a most unusual framework structure: instead of the expected 49· 66 topology …