Atomically precise control in the design of low-nuclearity supported metal catalysts

S Mitchell, J Pérez-Ramírez - Nature Reviews Materials, 2021 - nature.com
Nanostructured catalysts incorporating supported metal atoms or small clusters of defined
size and chemical composition attract considerable attention because of their potential to …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Advanced XPS characterization: XPS-based multi-technique analyses for comprehensive understanding of functional materials

MA Isaacs, J Davies-Jones, PR Davies… - Materials Chemistry …, 2021 - pubs.rsc.org
X-ray photoelectron spectroscopy (XPS) has achieved maturity as an analytical technique in
that it is a ubiquitous tool in the materials community, however as made apparent by recent …

Fluxionality of catalytic clusters: when it matters and how to address it

H Zhai, AN Alexandrova - ACS Catalysis, 2017 - ACS Publications
Small clusters secured at a given size, for example, via deposition on surfaces of
semiconductors, can be remarkable catalysts. In the so-called “non-scalable” regime, where …

Copper Cluster Size Effect in Methanol Synthesis from CO2

B Yang, C Liu, A Halder, EC Tyo… - The Journal of …, 2017 - ACS Publications
Size-selected Cu n catalysts (n= 3, 4, 20) were synthesized on Al2O3 thin films using mass-
selected cluster deposition. A systematic study of size and support effects was carried out for …

Ethylene Dehydrogenation on Pt4,7,8 Clusters on Al2O3: Strong Cluster Size Dependence Linked to Preferred Catalyst Morphologies

ET Baxter, MA Ha, AC Cass, AN Alexandrova… - Acs …, 2017 - ACS Publications
Catalytic dehydrogenation of ethylene on size-selected Pt n (n= 4, 7, 8) clusters deposited
on the surface of Al2O3 was studied experimentally and theoretically. Clusters were mass …

Boron Switch for Selectivity of Catalytic Dehydrogenation on Size-Selected Pt Clusters on Al2O3

MA Ha, ET Baxter, AC Cass, SL Anderson… - Journal of the …, 2017 - ACS Publications
Size-selected supported clusters of transition metals can be remarkable and highly tunable
catalysts. A particular example is Pt clusters deposited on alumina, which have been shown …

Electrocatalysis by Mass-Selected Ptn Clusters

A von Weber, SL Anderson - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Mass-selected Pt n+ ion deposition in ultrahigh vacuum (UHV) was used to
prepare a series of size-selected electrodes with Pt n (n≤ 14) clusters supported on either …

Metal-nanocluster science and technology: my personal history and outlook

Y Negishi - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Metal nanoclusters (NCs) are one of the leading targets in research of nanoscale materials,
and elucidation of their properties (science) and development of control techniques …

Inherent size effects on XANES of nanometer metal clusters: size-selected platinum clusters on silica

Y Dai, TJ Gorey, SL Anderson, S Lee… - The Journal of …, 2017 - ACS Publications
X-ray absorption near-edge structure (XANES) is commonly used to probe the oxidation
state of metal-containing nanomaterials; however, as the particle size in the material drops …