Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Methods that functionalize C–H bonds can lead to new approaches for the synthesis of
organic molecules, but to achieve this goal, researchers must develop site-selective …

A long-standing challenge in synthetic chemistry is the direct, selective functionalization of
alkyl, alkenyl, and aryl CH bonds. Much research has been devoted to the selective …

Alkenylboranes have been vital reagents in modern synthetic organic chemistry, whose
carbon–boron bond is transformable into a carbon–carbon bond stereoretentively to give …

In 1963 Shriver reported a metal-boron dative bond in a complex formulated as [(η5-C5H5)
2WH2 (BF3)]. 33 However, these findings were refuted around 30 years later when differing …

Multi (boronate) esters have been attracting increasing attention as versatile building blocks
for the succinct and precise synthesis of complex molecules. However, there are a limited …

Organoboronic acids and their derivatives are useful reagents in carbon–carbon and carbon–
heteroatom bond formations. 1 In addition to having reasonable reactivities, organoboronic …

Additions of homoelement-element and heteroelementelement linkages to unsaturated
substrates catalyzed by the platinum group metals constitute synthetically highly versatile …

Enantioenriched 1, 1-silylboryl alkanes possess silyl and boryl groups that are both
connected to the same stereogenic carbon center at well-defined orientations. As these …