Asymmetric arene hydrogenation: towards sustainability and application

L Lückemeier, M Pierau, F Glorius - Chemical Society Reviews, 2023 - pubs.rsc.org
(Hetero) aromatic compounds are vastly available and easy to functionalise building blocks
in the chemical industry. Asymmetric arene hydrogenation enables direct access to complex …

Organic synthesis using nitroxides

D Leifert, A Studer - Chemical Reviews, 2023 - ACS Publications
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Formic acid as a hydrogen storage material–development of homogeneous catalysts for selective hydrogen release

D Mellmann, P Sponholz, H Junge… - Chemical Society Reviews, 2016 - pubs.rsc.org
Formic acid (FA, HCO2H) receives considerable attention as a hydrogen storage material. In
this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction …

Supramolecular catalysis. Part 2: artificial enzyme mimics

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is
an intense subject of research. Non-covalent interactions are thought to be involved in …

Homochiral metal–organic frameworks for asymmetric heterogeneous catalysis

M Yoon, R Srirambalaji, K Kim - Chemical reviews, 2012 - ACS Publications
Chirality (handedness; left or right) is an intrinsic feature of various levels of matter. 1À4
Molecular chirality usually refers to a pair of molecules that cannot be superimposed onto …

Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

Engineering homochiral metal‐organic frameworks for heterogeneous asymmetric catalysis and enantioselective separation

Y Liu, W Xuan, Y Cui - Advanced Materials, 2010 - Wiley Online Library
Owing to the potential applications in technological areas such as gas storage, catalysis,
separation, sensing and nonlinear optics, tremendous efforts have been devoted to the …

Bridging the Gap between Industrial and Well‐Defined Supported Catalysts

C Copéret, F Allouche, KW Chan… - Angewandte Chemie …, 2018 - Wiley Online Library
Many industrial catalysts contain isolated metal sites on the surface of oxide supports.
Although such catalysts have been used in a broad range of processes for more than 40 …

Nitroxides: applications in synthesis and in polymer chemistry

L Tebben, A Studer - Angewandte Chemie International Edition, 2011 - Wiley Online Library
This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

Preparation of inorganic materials using ionic liquids

Z Ma, J Yu, S Dai - Advanced Materials, 2010 - Wiley Online Library
Conventional synthesis of inorganic materials relies heavily on water and organic solvents.
Alternatively, the synthesis of inorganic materials using, or in the presence of, ionic liquids …