Arylboron and arylphosphorus compounds represent privileged structural scaffolds in
synthetic chemistry for the construction of complex molecules. Transition-metal-mediated CB …

While the formation and breaking of transition metal (TM)–carbon bonds plays a pivotal role
in the catalysis of organic compounds, the reactivity of inorganometallic species, that is …

Decarbonylative synthesis of thioethers from thioesters proceeds in the presence of a
catalytic amount of [Rh (cod) Cl] 2 (2 mol%). The protocol represents the first Rh-catalyzed …

Transition metal‐catalyzed borylation has emerged as a powerful and versatile strategy for
synthesizing organoboron compounds. These compounds have found widespread …

This study reports the palladium‐catalyzed chemoselective borylation of (poly) halogenated
aryl triflates with a reactivity order of C− Cl> C− OTf. A catalyst system comprising Pd (OAc) 2 …

We report the rhodium-catalyzed base-free decarbonylative borylation of twisted amides.
The synthesis of versatile arylboronate esters from aryl twisted amides is achieved via …

Suzuki–Miyaura catalyst transfer polymerization (SM CTP) is a versatile method to prepare
conjugated polymers with control over molecular weight, sequence, and dispersity. This …

A dinucleating bis (β-diketiminate) ligand with a flexible bridge has been employed to
synthesize zinc complexes. The ligand, abbreviated H2L (H2L= N-(4-((2-((4-((2, 6 …

The application of a series of hydroxyl‐containing Schiff‐base ligands in the synthesis of
zinc complexes is reported. The substituents on the benzene rings, the positions of the C= N …