Helicenes: synthesis and applications

Y Shen, CF Chen - Chemical reviews, 2012 - ACS Publications
Helicenes are polycyclic aromatic compounds with nonplanar screw-shaped skeletons
formed by ortho-fused benzene or other aromatic rings. 1, 2 The first helicenes 1 and 2 …

One hundred years of helicene chemistry. Part 1: non-stereoselective syntheses of carbohelicenes

M Gingras - Chemical Society Reviews, 2013 - pubs.rsc.org
Carbohelicenes belong to a class of fascinating, chiral, and helicoidal molecules, which
have a rich history in chemistry since the very beginning of the 20th century. A renewed …

One hundred years of helicene chemistry. Part 2: stereoselective syntheses and chiral separations of carbohelicenes

M Gingras, G Félix, R Peresutti - Chemical Society Reviews, 2013 - pubs.rsc.org
Carbohelicenes generally incorporate a helical, distorted, conjugated, polyaromatic system
with ortho-fused benzenoid rings, which is a fundamental molecular characteristic of this …

Facile synthetic route to highly luminescent sila [7] helicene

H Oyama, K Nakano, T Harada, R Kuroda, M Naito… - Organic …, 2013 - ACS Publications
A facile synthetic route to dimethylsila [7] helicene by using a Lewis acid catalyzed double-
cyclization reaction for construction of the twisted two phenanthrene moieties is described …

Synthesis of [5]-, [6]-, and [7]Helicene via Ni(0)- or Co(I)-Catalyzed Isomerization of Aromatic cis,cis-Dienetriynes

F Teplý, IG Stará, I Starý, A Kollárovič… - Journal of the …, 2002 - ACS Publications
An original approach to helicene frameworks exploiting atom economic isomerization of
appropriate energy-rich aromatic cis, cis-dienetriynes has been developed. The new …

Enantioselective synthesis of helicenequinones and-bisquinones

A Urbano, MC Carreño - Organic & Biomolecular Chemistry, 2013 - pubs.rsc.org
A convergent approach based on Diels–Alder reactions between polycyclic dienes and
benzoquinones has emerged as a powerful tool for the construction of helicenequinones …

Carbocation Catalyzed Bromination of Alkyl Arenes, a Chemoselective sp3 vs. sp2 C−H functionalization.

S Ni, MAEAAA El Remaily… - Advanced Synthesis & …, 2018 - Wiley Online Library
The versatility of the trityl cation (TrBF4) as a highly efficient Lewis acid organocatalyst is
demonstrated in a light induced benzylic brominaion of alkyl‐arenes under mild conditions …

Enantiopure Dihydro-[5]-helicenequinones via Diels−Alder Reactions of Vinyl Dihydrophenanthrenes and (SS)-2-(p-Tolylsulfinyl)-1,4-benzoquinone

MC Carreño, S García-Cerrada… - Journal of the American …, 2001 - ACS Publications
The unique structure of helicenes1 makes them excellent candidates as new materials and
chiral auxiliaries in asymmetric synthesis. 2 The potential use of such species depends on …

Towards Configurationally Stable [4] Helicenes: Enantioselective Synthesis of 12‐Substituted 7, 8‐Dihydro [4] helicene Quinones

MC Carreno, Á Enríquez… - … A European Journal, 2008 - Wiley Online Library
The synthesis of enantiopure C‐12 methoxy‐or alkyl‐substituted 5, 7, 8, 12b‐tetrahydro [4]
helicene quinones 16 and 17 and the 7, 8‐dihydroaromatic analogues 4 and 5 has been …

From Central to Helical Chirality: Synthesis of P and M Enantiomers of [5]Helicenequinones and Bisquinones from (SS)‐2‐(p‐Tolylsulfinyl)‐ 1,4‐benzoquinone

MC Carreño, S García‐Cerrada… - Chemistry–A European …, 2003 - Wiley Online Library
Abstract The reaction of 1, 4‐divinyl‐1, 3‐cyclohexadiene, 5, 8‐dimethoxy‐or tert‐
butyldimethylsilyloxy‐3‐vinyl‐1, 2‐dihydrophenanthrene or 6‐vinyl‐7, 8‐dihydro‐1, 4 …