Organic contaminant transport and fate in the subsurface: Evolution of knowledge and understanding

HI Essaid, BA Bekins… - Water Resources Research, 2015 - Wiley Online Library
Toxic organic contaminants may enter the subsurface as slightly soluble and volatile
nonaqueous phase liquids (NAPLs) or as dissolved solutes resulting in contaminant plumes …

Mixing and reactive fronts in the subsurface

M Rolle, T Le Borgne - Reviews in Mineralogy and …, 2019 - pubs.geoscienceworld.org
The interplay between mixing and reactive processes plays a pivotal role in a range of
biogeochemical processes controlling the transport, transformation and turnover of chemical …

Mixing-limited reactions in porous media

AJ Valocchi, D Bolster, CJ Werth - Transport in Porous Media, 2019 - Springer
Mixing-driven reactions in porous media are ubiquitous and span natural and engineered
environments, yet predicting where and how quickly reactions occur is immensely …

The lamellar description of mixing in porous media

T Le Borgne, M Dentz, E Villermaux - Journal of Fluid Mechanics, 2015 - cambridge.org
We develop a general framework for modelling mixing in porous media flows, in which the
scalar mixture is represented as an ensemble of lamellae evolving through stretching …

On the importance of diffusion and compound-specific mixing for groundwater transport: An investigation from pore to field scale

M Rolle, G Chiogna, DL Hochstetler… - Journal of contaminant …, 2013 - Elsevier
Mixing processes significantly affect and limit contaminant transport and transformation rates
in the subsurface. The correct quantification of mixing in groundwater systems must account …

Enhanced mixing and reaction in converging flows: Theory and pore‐scale imaging

S Izumoto, J Heyman, JA Huisman… - Water Resources …, 2023 - Wiley Online Library
Mixing fronts at the interface of opposing flows are compressed at a constant rate. The
resulting exponential stretching of fluid elements leads to enhanced chemical gradients and …

Controlling pore-scale processes to tame subsurface biomineralization

J Jimenez-Martinez, J Nguyen, D Or - Reviews in Environmental Science …, 2022 - Springer
Microorganisms capable of biomineralization can catalyze mineral precipitation by
modifying local physical and chemical conditions. In porous media, such as soil and rock …

Experiments and simulations on plume spreading by engineered injection and extraction in refractive index matched porous media

LJ Sather, EJ Roth, RM Neupauer… - Water Resources …, 2023 - Wiley Online Library
Engineered injection and extraction (EIE) is an in situ groundwater remediation strategy that
imposes an engineered spatially and temporally varying velocity field to spread an …

Enhanced reaction kinetics and reactive mixing scale dynamics in mixing fronts under shear flow for arbitrary Damköhler numbers

A Bandopadhyay, T Le Borgne, Y Méheust… - Advances in water …, 2017 - Elsevier
Mixing fronts, where fluids of different chemical compositions mix with each other, are known
to represent hotspots of chemical reaction in hydrological systems. These fronts are typically …

Engineered injection and extraction to enhance reaction for improved in situ remediation

AN Piscopo, RM Neupauer… - Water Resources …, 2013 - Wiley Online Library
During in situ remediation, a treatment solution is often injected into a contaminated aquifer
to degrade the groundwater contaminant. Since contaminant degradation reactions occur …