The role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts

LM Rossi, JL Fiorio, MAS Garcia, CP Ferraz - Dalton Transactions, 2018 - pubs.rsc.org
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …

Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis

D Astruc, F Lu, JR Aranzaes - … Chemie International Edition, 2005 - Wiley Online Library
Interest in catalysis by metal nanoparticles (NPs) is increasing dramatically, as reflected by
the large number of publications in the last five years. This field,“semi‐heterogeneous …

Removal and utilization of capping agents in nanocatalysis

Z Niu, Y Li - Chemistry of Materials, 2014 - ACS Publications
Capping agents are frequently used in colloidal synthesis to inhibit nanoparticle overgrowth
and aggregation as well as to control the structural characteristics of the resulted …

Surface and interface control of noble metal nanocrystals for catalytic and electrocatalytic applications

B Wu, N Zheng - Nano Today, 2013 - Elsevier
Catalysis and electrocatalysis by noble metal (NM) nanomaterials is typically surface and
interface-sensitive. Effective surface and interface control over NM nanomaterials provides …

Beyond Conventional N-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

O Schuster, L Yang, HG Raubenheimer… - Chemical …, 2009 - ACS Publications
The organometallic chemistry of N-heterocyclic carbenes (NHCs) has experienced
explosive development during the last few years, and the topic remains the main focus of …

The role of palladium nanoparticles in catalytic C–C cross-coupling reactions

AM Trzeciak, AW Augustyniak - Coordination Chemistry Reviews, 2019 - Elsevier
This review describes the recent advances in understanding of the mechanism of palladium
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …

Untangling the role of the capping agent in nanocatalysis: recent advances and perspectives

S Campisi, M Schiavoni, CE Chan-Thaw, A Villa - Catalysts, 2016 - mdpi.com
Capping agents (organic ligands, polymers, surfactants, etc.) are a basic component in the
synthesis of metal nanoparticles with controlled size and well-defined shape. However, their …

Metal@ MOF: loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition

S Hermes, MK Schröter, R Schmid… - Angewandte Chemie …, 2005 - Wiley Online Library
Standing out from the vast majority of metal organic coordination polymers is the class of
highly porous basic zinc carboxylates developed by Yaghi and co-workers.[1] Its prototype is …

Asymmetric catalysis at chiral metal surfaces

T Mallat, E Orglmeister, A Baiker - Chemical Reviews, 2007 - ACS Publications
The remarkable development in homogeneous enantioselective catalysis reflected by the
Nobel prizes in 2001 awarded to Sharpless, Noyori, and Knowles has further spurred the …

Chemical synthesis and application of palladium nanoparticles

I Saldan, Y Semenyuk, I Marchuk… - Journal of Materials …, 2015 - Springer
In the past, palladium as a member of the platinum group metals was mainly known as an
expensive noble metal. Probably, only fast hydrogen absorption into bulk palladium …