The role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …
engineering of nanomaterials' size, shape and surface composition, including adsorbed …
Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis
D Astruc, F Lu, JR Aranzaes - … Chemie International Edition, 2005 - Wiley Online Library
Interest in catalysis by metal nanoparticles (NPs) is increasing dramatically, as reflected by
the large number of publications in the last five years. This field,“semi‐heterogeneous …
the large number of publications in the last five years. This field,“semi‐heterogeneous …
Removal and utilization of capping agents in nanocatalysis
Z Niu, Y Li - Chemistry of Materials, 2014 - ACS Publications
Capping agents are frequently used in colloidal synthesis to inhibit nanoparticle overgrowth
and aggregation as well as to control the structural characteristics of the resulted …
and aggregation as well as to control the structural characteristics of the resulted …
Surface and interface control of noble metal nanocrystals for catalytic and electrocatalytic applications
Catalysis and electrocatalysis by noble metal (NM) nanomaterials is typically surface and
interface-sensitive. Effective surface and interface control over NM nanomaterials provides …
interface-sensitive. Effective surface and interface control over NM nanomaterials provides …
Beyond Conventional N-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization
O Schuster, L Yang, HG Raubenheimer… - Chemical …, 2009 - ACS Publications
The organometallic chemistry of N-heterocyclic carbenes (NHCs) has experienced
explosive development during the last few years, and the topic remains the main focus of …
explosive development during the last few years, and the topic remains the main focus of …
The role of palladium nanoparticles in catalytic C–C cross-coupling reactions
AM Trzeciak, AW Augustyniak - Coordination Chemistry Reviews, 2019 - Elsevier
This review describes the recent advances in understanding of the mechanism of palladium
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …
Untangling the role of the capping agent in nanocatalysis: recent advances and perspectives
S Campisi, M Schiavoni, CE Chan-Thaw, A Villa - Catalysts, 2016 - mdpi.com
Capping agents (organic ligands, polymers, surfactants, etc.) are a basic component in the
synthesis of metal nanoparticles with controlled size and well-defined shape. However, their …
synthesis of metal nanoparticles with controlled size and well-defined shape. However, their …
Metal@ MOF: loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition
S Hermes, MK Schröter, R Schmid… - Angewandte Chemie …, 2005 - Wiley Online Library
Standing out from the vast majority of metal organic coordination polymers is the class of
highly porous basic zinc carboxylates developed by Yaghi and co-workers.[1] Its prototype is …
highly porous basic zinc carboxylates developed by Yaghi and co-workers.[1] Its prototype is …
Asymmetric catalysis at chiral metal surfaces
T Mallat, E Orglmeister, A Baiker - Chemical Reviews, 2007 - ACS Publications
The remarkable development in homogeneous enantioselective catalysis reflected by the
Nobel prizes in 2001 awarded to Sharpless, Noyori, and Knowles has further spurred the …
Nobel prizes in 2001 awarded to Sharpless, Noyori, and Knowles has further spurred the …
Chemical synthesis and application of palladium nanoparticles
In the past, palladium as a member of the platinum group metals was mainly known as an
expensive noble metal. Probably, only fast hydrogen absorption into bulk palladium …
expensive noble metal. Probably, only fast hydrogen absorption into bulk palladium …