Molecular views on Fischer–Tropsch synthesis

KT Rommens, M Saeys - Chemical Reviews, 2023 - ACS Publications
For nearly a century, the Fischer–Tropsch (FT) reaction has been subject of intense debate.
Various molecular views on the active sites and on the reaction mechanism have been …

Cobalt catalysts on carbon-based materials for Fischer-Tropsch synthesis: a review

AC Ghogia, A Nzihou, P Serp, K Soulantica… - Applied Catalysis A …, 2021 - Elsevier
This review analyzes the literature from the 80's to the beginning of 2020 and covers the use
of carbon materials as supports for cobalt-based catalysts used in the Fischer Tropsch …

Structure Sensitivity of CO2 Hydrogenation on Ni Revisited

JFM Simons, TJ de Heer, RCJ van de Poll… - Journal of the …, 2023 - ACS Publications
Despite the large number of studies on the catalytic hydrogenation of CO2 to CO and
hydrocarbons by metal nanoparticles, the nature of the active sites and the reaction …

Mechanistic study of low temperature CO2 methanation over Rh/TiO2 catalysts

A Karelovic, P Ruiz - Journal of Catalysis, 2013 - Elsevier
CO2 methanation at low temperature and atmospheric pressure was studied over Rh/TiO2
catalysts focusing on the effect of Rh particle size on the activity and reaction mechanism …

[HTML][HTML] Mechanism and microkinetics of the Fischer–Tropsch reaction

RA Van Santen, AJ Markvoort, IAW Filot… - Physical Chemistry …, 2013 - pubs.rsc.org
The increasing availability of quantum-chemical data on surface reaction intermediates
invites one to revisit unresolved mechanistic issues in heterogeneous catalysis. One such …

Size-dependent dissociation of carbon monoxide on cobalt nanoparticles

A Tuxen, S Carenco, M Chintapalli… - Journal of the …, 2013 - ACS Publications
In situ soft X-ray absorption spectroscopy (XAS) was employed to study the adsorption and
dissociation of carbon monoxide molecules on cobalt nanoparticles with sizes ranging from …

Size effects of ZnO nanoparticles in bifunctional catalysts for selective syngas conversion

N Li, F Jiao, X Pan, Y Ding, J Feng, X Bao - ACS Catalysis, 2018 - ACS Publications
The oxide–zeolite (OX–ZEO) bifunctional catalyst design concept has shown promising
potential for selectivity control in syngas conversion by separating CO activation and C–C …

Influence on nickel particle size on the hydrodeoxygenation of phenol over Ni/SiO2

PM Mortensen, JD Grunwaldt, PA Jensen, AD Jensen - Catalysis Today, 2016 - Elsevier
Hydrodeoxygenation (HDO) of phenol over nickel nano-particles of different size (5–22 nm)
supported on SiO 2 has been investigated in a batch reactor at 275° C and 100 bar …

Mechanistic Connections between CO2 and CO Hydrogenation on Dispersed Ruthenium Nanoparticles

H Mansour, E Iglesia - Journal of the American Chemical Society, 2021 - ACS Publications
Catalytic routes for upgrading CO2 to CO and hydrocarbons have been studied for decades,
and yet the mechanistic details and structure–function relationships that control catalytic …

Recent approaches in mechanistic and kinetic studies of catalytic reactions using SSITKA technique

C Ledesma, J Yang, D Chen, A Holmen - Acs Catalysis, 2014 - ACS Publications
One of the most useful techniques to obtain valuable information on catalyzed
heterogeneous reactions at, or near to, molecular level is the Steady-State Isotopic Transient …