Design and synthesis of coordination polymers with chelated units and their application in nanomaterials science

GI Dzhardimalieva, IE Uflyand - RSC advances, 2017 - pubs.rsc.org
The advances and problems associated with the preparation, properties and structure of
coordination polymers with chelated units are presented and assessed. The metalloligand …

Porphyrin polymers and organic frameworks

NU Day, CC Wamser, MG Walter - Polymer International, 2015 - Wiley Online Library
The versatility of porphyrins as optoelectronic or catalytic units makes them attractive
elements for inclusion in functional materials. Polymers that include porphyrins have been …

Otherwise unstable structures self-assemble in the cavities of cuboctahedral coordination cages

FJ Rizzuto, WJ Ramsay… - Journal of the American …, 2018 - ACS Publications
We present a method for the directed self-assembly of interlocked structures and
coordination complexes in a set of metal–organic hosts. New homo-and heteroleptic metal …

[HTML][HTML] Synthesis, structure, photophysical properties and biological activity of a cobalt (II) coordination complex with 4, 4′-bipyridine and porphyrin chelating ligands

N Amiri, S Nouir, M Hajji, T Roisnel, T Guerfel… - Journal of Saudi …, 2019 - Elsevier
A new bioactive material of cobalt (II) with 5, 10, 15, 20-tetrakis [4 (benzoyloxy) phenyl]
porphyrin (TPBP) and bpy ligands ([Co II (TPBP)(bpy) 2] 1) has been synthesized and …

Temperature-Variant CO2 Separation in Entangled Metal-Organic Framework with Carboxamide Functionality-Fueled Atmospheric-Pressure Cycloaddition and Size …

PP Mondal, S Sarkar, M Singh… - … Sustainable Chemistry & …, 2024 - ACS Publications
The pressing need to lower atmospheric carbon dioxide (CO2) concentration has captivated
global focus on point-source capture and transformation of this greenhouse gas to …

A new Zn (ii) MOF assembled from metal–organic cubes (MOCs) as a highly efficient adsorbent for cationic dyes

A Siddique, I Mantasha, P Rawat, RN Singh… - …, 2021 - pubs.rsc.org
The process of assembling astutely designed well-defined metal–organic cubes (MOCs) is
attracting considerable attention due to their rare networks and topologies. A novel 3D self …

Proton mediated spin state transition of cobalt heme analogs

J Zhao, Q Peng, Z Wang, W Xu, H Xiao, Q Wu… - Nature …, 2019 - nature.com
The spin state transition from low spin to high spin upon substrate addition is one of the key
steps in cytochrome P450 catalysis. External perturbations such as pH and hydrogen …

High selective photocatalytic CO2 conversion into liquid solar fuel over a cobalt porphyrin-based metal–organic framework

N Sadeghi, M Sillanpää - Photochemical & Photobiological Sciences, 2021 - Springer
In the present study, porphyrin-based metal–organic framework (Co/PMOF) was synthesized
and characterized by different spectra analyses. The photoluminescence properties of …

Heteroleptic cobalt (II) complex with nitrogen-rich macrocycles—Structure, bioactivity and DFT modelling

M Hajji, N Amiri, FB Taheur, A Bujacz, H Nasri… - Solid State …, 2020 - Elsevier
We herein discuss the synthesis and characterization of a novel mononuclear cobalt (II)
complex Co II (TPBP)(HTMA) 2 with the N-donor ligands; hexamethylenetetramine HTMA …

Effect of mesoporous chitosan action and coordination on the catalytic activity of mesoporous chitosan-grafted cobalt tetrakis (p-sulfophenyl) porphyrin for …

G Huang, LQ Mo, YX Wei, H Zhou, YA Guo, SJ Wei - Catalysts, 2018 - mdpi.com
To simulate the active site cavity structure function and axial coordination of cytochrome P-
450 enzymes, mesoporous chitosan (mesp-CTS) was used as a scaffold for a meso-sized …