Distortion pathways of transition metal coordination polyhedra induced by chelating topology

S Alvarez - Chemical Reviews, 2015 - ACS Publications
A continuous shape measures analysis of the coordination polyhedra of a host of transition
metal complexes with bi-and multidentate ligands discloses the distortion pathway …

Anion⋯ anion self-assembly under the control of σ-and π-hole bonds

A Pizzi, A Dhaka, R Beccaria, G Resnati - Chemical Society Reviews, 2024 - pubs.rsc.org
The electrostatic attraction between charges of opposite signs and the repulsion between
charges of the same sign are ubiquitous and influential phenomena in recognition and self …

Expanding the dimensionality of bis (tetrazolyl) alkane-based Fe (ii) coordination polymers by the application of dinitrile coligands

A Tołoczko, M Kaźmierczak, M Książek… - Dalton …, 2024 - pubs.rsc.org
Reactions between 1, 2-di (tetrazol-2-yl) ethane (ebtz), 1, 6-di (tetrazol-2-yl) hexane (hbtz) or
1, 1′-di (tetrazol-1-yl) methane (1ditz) and Fe (BF4) 2 in the presence of adiponitrile (ADN) …

Role of Fe–N–C Geometry Flip-Flop in Bistability in Fe(tetrazol-2-yl)4(C2H5CN)2-Type Core Based Coordination Network

A Białońska, R Bronisz - Inorganic Chemistry, 2012 - ACS Publications
[Fe (ebtz) 2 (C2H5CN) 2](ClO4) 2 was prepared in the reaction of 1, 2-di (tetrazol-2-yl)
ethane (ebtz) with Fe (ClO4) 2· 6H2O in propionitrile. The compound crystallizes as a one …

Influence of conformational changes on spin crossover properties and superstructure formation in 2D coordination polymers [Fe (hbtz) 2 (RCN) 2](ClO 4) 2

M Książek, J Kusz, A Białońska, R Bronisz… - Dalton …, 2015 - pubs.rsc.org
2D structurally related iron (II) coordination networks {[Fe (hbtz) 2 (RCN) 2](ClO4) 2}∞
featuring, besides tetrazol-2-yl rings in the first coordination sphere, also axially coordinated …

Spin crossover Fe (II) complexes of a cross-bridged cyclam derivative

B Drahoš, Z Trávníček - Dalton Transactions, 2018 - pubs.rsc.org
A cross-bridged cyclam derivative containing two 2-pyridylmethyl pendant arms (L= 4, 11-bis
((pyridin-2-yl) methyl)-1, 4, 8, 11-tetraaza-bicyclo [6.6. 2] hexadecane) was synthesized by …

Self-assembly of three-dimensional oxalate-bridged alkali (I)–lanthanide (III) heterometal–organic frameworks

N Ponjan, F Kielar, W Dungkaew, K Kongpatpanich… - …, 2020 - pubs.rsc.org
Three isostructural three-dimensional (3D) oxalate bridged alkali (I)–lanthanide (III)
heterometal–organic frameworks with the general formula [Ln8Na4 (ox) 10 (μ3-OH) 8] …

1D Spin‐Crossover Networks Containing a FeII(1,2,3‐triazol‐1‐yl)4(CH3CN)2‐Type Core

A Białońska, R Bronisz… - European Journal of …, 2013 - Wiley Online Library
Abstract Bis (1, 2, 3‐triazol‐1‐yl) methane (mbtr) was used to prepare 1D networks in which
neighboring iron (II) ions are tethered by two semiflexible ligand molecules.[Fe (mbtr) 2 …

Polymeric Spin‐Crossover Materials

M Carmen Muñoz… - Spin‐Crossover Materials …, 2013 - Wiley Online Library
This chapter on polymeric spin‐crossover (SCO) materials provides a survey of 1‐, 2‐and 3‐
dimensional (1‐3D) SCO coordination polymers (nD‐SCO‐CPs) reported in the period 2004 …

Synthesis and Characterization of a 2D Cobalt (II) Coordination Polymer Containing the Adiponitrile Ligand

K Chainok, W Saphu, P Khemthong… - … für anorganische und …, 2013 - Wiley Online Library
The cobalt (II) coordination polymer [Co (ADN) 3][FeCl4] 2 (1), which contains a flexible
dinitrile bridging ligand was synthesized at room temperature from the 1: 2: 3 reaction of …