Quantum mechanical basis for kinetic diameters of small gaseous molecules

N Mehio, S Dai, D Jiang - The Journal of Physical Chemistry A, 2014 - ACS Publications
Kinetic diameters are often invoked in discussing gas adsorption and permeation in porous
and polymeric materials. However, how these empirical kinetic diameters relate to the size …

An Ongoing Futuristic Career of Metal–Organic Frameworks and Ionic Liquids, A Magical Gateway to Capture CO2; A Critical Review

SA Ali, AU Khan, WU Mulk, H Khan, S Nasir Shah… - Energy & …, 2023 - ACS Publications
Carbon capture and storage (CCS) technologies are the “knight in shining armor” that can
save humanity from burnout in the longer term, minimizing damage from CO2 emissions by …

Interactions of CO 2 with various functional molecules

HM Lee, IS Youn, M Saleh, JW Lee… - Physical Chemistry …, 2015 - pubs.rsc.org
The CO2 capturing and sequestration are of importance in environmental science.
Understanding of the CO2-interactions with various functional molecules including multi-N …

Ionic polyimides: hybrid polymer architectures and composites with ionic liquids for advanced gas separation membranes

MS Mittenthal, BS Flowers, JE Bara… - Industrial & …, 2017 - ACS Publications
Polyimides and ionic liquids (ILs) are two classes of materials that have been widely studied
as gas separation membranes, each demonstrating respective advantages and limitations …

Highly Selective Capture of CO2 by Ether-Functionalized Pyridinium Ionic Liquids with Low Viscosity

S Zeng, J Wang, L Bai, B Wang, H Gao, D Shang… - Energy & …, 2015 - ACS Publications
In this work, three kinds of ether-functionalized pyridinium-based ILs [E n Py][NTf2] with low
viscosity were designed and synthesized and used for highly selective separation of CO2 …

Solubility and diffusivity of oxygen in ionic liquids

T Song, O Morales-Collazo… - Journal of Chemical & …, 2019 - ACS Publications
The solubility of O2 was measured gravimetrically in 16 ionic liquids (ILs) containing
piperidinium, pyrrolidinium, ammonium, tetrahydrothiophenium, methyltriazabicyclodecene …

Chemical and Physical Absorption of SO2 by N-Functionalized Imidazoles: Experimental Results and Molecular-level Insight

MS Shannon, AC Irvin, H Liu, JD Moon… - Industrial & …, 2015 - ACS Publications
Sulfur dioxide (SO2) removal is a key component of many industrial processes, especially
coal-fired power generation. Controlling SO2 emissions is vital to maintaining environmental …

Correlating fractional free volume to CO2 selectivity in [Rmim][Tf2N] ionic liquids

WJ Horne, MS Shannon, JE Bara - The Journal of Chemical …, 2014 - Elsevier
Ionic liquids (ILs) with smaller molar volumes are typically correlated with improved CO 2/N
2 and CO 2/CH 4 solubility selectivity. However, it is the free volume (ie the “empty” space) …

1,2,3-Trimethoxypropane: A Glycerol-Derived Physical Solvent for CO2 Absorption

BS Flowers, MS Mittenthal, AH Jenkins… - ACS Sustainable …, 2017 - ACS Publications
1, 2, 3-Trimethoxypropane (1, 2, 3-TMP) is the trimethyl ether of propane-1, 2, 3-triol, better
known as glycerol, which can be derived from triglycerides originating from either plant or …

A new class of single‐component absorbents for reversible carbon dioxide capture under mild conditions

F Barzagli, S Lai, F Mani - ChemSusChem, 2015 - Wiley Online Library
Some inexpensive and commercially available secondary amines reversibly react with CO2
at room temperature and ambient pressure to yield carbonated species in the liquid phase in …