Chemomechanics of rechargeable batteries: status, theories, and perspectives

LS de Vasconcelos, R Xu, Z Xu, J Zhang… - Chemical …, 2022 - ACS Publications
Chemomechanics is an old subject, yet its importance has been revived in rechargeable
batteries where the mechanical energy and damage associated with redox reactions can …

An Overview on the Advances of LiCoO2 Cathodes for Lithium‐Ion Batteries

Y Lyu, X Wu, K Wang, Z Feng, T Cheng… - Advanced Energy …, 2021 - Wiley Online Library
LiCoO2, discovered as a lithium‐ion intercalation material in 1980 by Prof. John B.
Goodenough, is still the dominant cathode for lithium‐ion batteries (LIBs) in the portable …

Interfacial Design for a 4.6 V High‐Voltage Single‐Crystalline LiCoO2 Cathode

J Zhang, PF Wang, P Bai, H Wan, S Liu… - Advanced …, 2022 - Wiley Online Library
Single‐crystalline cathode materials have attracted intensive interest in offering greater
capacity retention than their polycrystalline counterparts by reducing material surfaces and …

Structural Understanding for High‐Voltage Stabilization of Lithium Cobalt Oxide

C Lin, J Li, ZW Yin, W Huang, Q Zhao… - Advanced …, 2024 - Wiley Online Library
The rapid development of modern consumer electronics is placing higher demands on the
lithium cobalt oxide (LiCoO2; LCO) cathode that powers them. Increasing operating voltage …

[HTML][HTML] 3D microstructure design of lithium-ion battery electrodes assisted by X-ray nano-computed tomography and modelling

X Lu, A Bertei, DP Finegan, C Tan, SR Daemi… - Nature …, 2020 - nature.com
Driving range and fast charge capability of electric vehicles are heavily dependent on the 3D
microstructure of lithium-ion batteries (LiBs) and substantial fundamental research is …

Tailoring Co3d and O2p Band Centers to Inhibit Oxygen Escape for Stable 4.6 V LiCoO2 Cathodes

W Kong, J Zhang, D Wong, W Yang, J Yang… - Angewandte …, 2021 - Wiley Online Library
High‐voltage LiCoO2 delivers a high capacity but sharp fading is a critical issue, and the
capacity decay mechanism is also poorly understood. Herein, we clarify that the escape of …

Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V

JN Zhang, Q Li, C Ouyang, X Yu, M Ge, X Huang, E Hu… - Nature Energy, 2019 - nature.com
LiCoO2 is a dominant cathode material for lithium-ion (Li-ion) batteries due to its high
volumetric energy density, which could potentially be further improved by charging to high …

Unveiling the Evolution of LiCoO2 beyond 4.6 V

Z Wu, G Zeng, J Yin, CL Chiang, Q Zhang… - ACS Energy …, 2023 - ACS Publications
The working mechanism of LiCoO2 beyond 4.6 V presents complicated issues:(1) the
ambiguous multistructural evolutions,(2) the vague O-related anionic redox reactions (ARR) …

Evolution of redox couples in Li-and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release

E Hu, X Yu, R Lin, X Bi, J Lu, S Bak, KW Nam, HL Xin… - Nature Energy, 2018 - nature.com
Voltage fade is a major problem in battery applications for high-energy lithium-and
manganese-rich (LMR) layered materials. As a result of the complexity of the LMR structure …

Review of recent development of in situ/operando characterization techniques for lithium battery research

D Liu, Z Shadike, R Lin, K Qian, H Li, K Li… - Advanced …, 2019 - Wiley Online Library
The increasing demands of energy storage require the significant improvement of current Li‐
ion battery electrode materials and the development of advanced electrode materials. Thus …