The fragmentation pathways of protonated peptides are reviewed in the present paper
paying special attention to classification of the known fragmentation channels into a simple …

Boron cations are elusive and highly electrophilic species that play a key role in the
chemistry of boron. Despite early interest in the chemistry of boron cations, until recently they …

Molecular mass spectrometry continues to show an exponential growth, with a substantial
proportion of its applications still requiring the identification of unknown mass spectra. The …

The only comprehensive guide to CIMS applications in structural elucidation and analytical
studiesChemical Ionization Mass Spectrometry, 2nd Edition, provides a comprehensive, up …

Under appropriate conditions, the kinetics of the dissociation of molecular cluster ions can
yield relative, but quantitative, thermochemical information on the constituent species …

The methods of establishing gas‐phase basicities and proton affinities are reviewed,
particularly as applied to thermally labile and involatile molecules. The literature on the …

The temperature dependence of equilibrium constants A/_u „for reactions H30+(H20)^ 1+
H20= H30+(H20)„was determined in a pulsed electron beam high ion source pressure mass …

Publisher Summary This chapter provides a large collection of solution data and a
thoroughly updated discussion of thermodynamic, kinetic, and structural results. This chapter …

The proton is the smallest and the lightest atomic nucleus and is the most abundant in the
universe. Notwithstanding its minute size, it plays gargantuan roles in chemistry …

Comparison of measured stabilities with “magic” numbers in the cluster ion size distribution
and with total CID cross sections shows that neither is a reliable indicator of stability. We …