The chemistry of binuclear palladium (II) and platinum (II) complexes

VK Jain, L Jain - Coordination Chemistry Reviews, 2005 - Elsevier
The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …

An overview of the chemistry of homo and heteropolynuclear platinum complexes containing bridging acetylide (μ-C≡ CR) ligands

JR Berenguer, E Lalinde, MT Moreno - Coordination Chemistry Reviews, 2010 - Elsevier
Different aspects of transition metal alkynyl chemistry have been widely studied over the
past decades because of their interesting structures, chemical reactivity and properties. This …

Using triethynylphosphine ligands bearing bulky end caps to create a holey catalytic environment: Application to gold (I)-catalyzed alkyne cyclizations

A Ochida, H Ito, M Sawamura - Journal of the American Chemical …, 2006 - ACS Publications
The synthesis, properties and catalytic uses of phosphinoalkynes bearing bulky end caps at
the alkyne termini, that is, tris [(triarylsilyl) ethynyl] phosphines are reported. The most salient …

New approach to phosphinoalkynes based on Pd-and Ni-catalyzed cross-coupling of terminal alkynes with chlorophosphanes

IP Beletskaya, VV Afanasiev, MA Kazankova… - Organic …, 2003 - ACS Publications
The first example of direct phosphination of terminal alkynes with chlorophosphanes
catalyzed by Ni or Pd complexes is described. Both aromatic and aliphatic terminal …

Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt (i) complex [(PHCy 2) Pt (μ-PCy 2){κ 2 P, O-μ-P (O) Cy 2} Pt (PHCy 2)](Pt–Pt)

S Todisco, M Latronico, V Gallo, N Re, A Marrone… - Dalton …, 2020 - pubs.rsc.org
The reaction of the dinuclear phosphinito bridged complex [(PHCy2) Pt (μ-PCy2){κ2P, O-μ-P
(O) Cy2} Pt (PHCy2)](Pt–Pt)(1) with phenylacetylene affords the η1-alkenyl-μ, η1: η2-alkynyl …

19F NMR in organometallic chemistry: Applications of fluorinated aryls

P Espinet, AC Albéniz, JA Casares… - Coordination Chemistry …, 2008 - Elsevier
The applications of 19F NMR in the study of a number of problems in organometallic
chemistry are illustrated with relevant cases, paying special attention to the case of …

Homo‐and Heteropolynuclear Platinum Complexes Stabilized by Dimethylpyrazolato and Alkynyl Bridging Ligands: Synthesis, Structures, and Luminescence

J Forniés, S Fuertes, A Martín, V Sicilia… - … A European Journal, 2006 - Wiley Online Library
This work describes the synthesis of cis‐[Pt (C CPh) 2 (Hdmpz) 2](1) and its use as a
precursor for the preparation of homo‐and heteropolynuclear complexes. Double …

Phosphorus Ligands with a Large Cavity: Synthesis of Triethynylphosphines with Bulky End Caps and Application to the Rhodium‐Catalyzed Hydrosilylation of …

A Ochida, M Sawamura - Chemistry–An Asian Journal, 2007 - Wiley Online Library
Trialkynylphosphines substituted with bulky triarylsilyl groups at the alkyne termini were
synthesized. The new phosphines P (C CSiAr3) 3 (Ar= 3, 5‐tBu2‐4‐MeOC6H2, 3, 5 …

Nickel(II) and Palladium(II) Thiaethyneporphyrins. Intramolecular Metal(II)−η2-CC Interaction inside a Porphyrinoid Frame

E Nojman, A Berlicka, L Szterenberg… - Inorganic …, 2012 - ACS Publications
3, 18-Diphenyl-8, 13-di-p-tolyl-20-thiaethyneporphyrin ([18] thiatriphyrin (4.1. 1)), which
formally contains an C1–C2 ethyne moiety instead of pyrrole embedded in the macrocyclic …

Discrete Triangle, Square and Hexametallic Alkynyl Cyano‐Bridged Compounds Based on [cis‐Pt(CCR)2(CN)2]2− Building Blocks

J Forniés, J Gómez, E Lalinde… - Chemistry–A European …, 2004 - Wiley Online Library
Novel mixed bis (alkynyl) bis (cyano) platinate (ii) species [cis‐Pt (C CR) 2 (CN) 2] 2−(1 a:
R= tBu, 1 b: R= Ph) have been prepared and their potential as building blocks in the …