Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR
T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …
biology. While NMR can provide invaluable information about local geometry on an atomic …
[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …
diversification since its inception more than 6 decades ago. In this review we provide an in …
High frequency dynamic nuclear polarization
During the three decades 1980–2010, magic angle spinning (MAS) NMR developed into the
method of choice to examine many chemical, physical, and biological problems. In …
method of choice to examine many chemical, physical, and biological problems. In …
Efficient dynamic nuclear polarization at 800 MHz/527 GHz with trityl‐nitroxide biradicals
Cross‐effect (CE) dynamic nuclear polarization (DNP) is a rapidly developing technique that
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …
Theory for cross effect dynamic nuclear polarization under magic-angle spinning in solid state nuclear magnetic resonance: The importance of level crossings
KR Thurber, R Tycko - The Journal of chemical physics, 2012 - pubs.aip.org
We present theoretical calculations of dynamic nuclear polarization (DNP) due to the cross
effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin …
effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin …
Overhauser effects in insulating solids
BACKGROUND Part of our results (vide infra) share a characteristic feature with the
Overhauser effect in solution where an enhancement is observed around the electron …
Overhauser effect in solution where an enhancement is observed around the electron …
Computationally assisted design of polarizing agents for dynamic nuclear polarization enhanced NMR: the AsymPol family
F Mentink-Vigier, I Marin-Montesinos… - Journal of the …, 2018 - ACS Publications
We introduce a new family of highly efficient polarizing agents for dynamic nuclear
polarization (DNP)-enhanced nuclear magnetic resonance (NMR) applications, composed …
polarization (DNP)-enhanced nuclear magnetic resonance (NMR) applications, composed …
Nuclear depolarization and absolute sensitivity in magic-angle spinning cross effect dynamic nuclear polarization
Over the last two decades solid state Nuclear Magnetic Resonance has witnessed a
breakthrough in increasing the nuclear polarization, and thus experimental sensitivity, with …
breakthrough in increasing the nuclear polarization, and thus experimental sensitivity, with …
Dynamic nuclear polarization with a rigid biradical
A new polarizing agent with superior performance in dynamic nuclear polarization
experiments is introduced, and utilizes two TEMPO (2, 2, 6, 6‐tetramethylpiperidine‐1‐oxyl) …
experiments is introduced, and utilizes two TEMPO (2, 2, 6, 6‐tetramethylpiperidine‐1‐oxyl) …
Theoretical aspects of dynamic nuclear polarization in the solid state–the cross effect
Y Hovav, A Feintuch, S Vega - Journal of Magnetic Resonance, 2012 - Elsevier
In recent years Dynamic Nuclear Polarization (DNP) signal enhancement techniques have
become an important and integral part of modern NMR and MRI spectroscopy. The DNP …
become an important and integral part of modern NMR and MRI spectroscopy. The DNP …