The new era of high-throughput nanoelectrochemistry

X Xu, D Valavanis, P Ciocci, S Confederat… - Analytical …, 2023 - ACS Publications
To acquire a deeper understanding of electrochemical systems requires techniques that
address nanoscale aspects of electrochemistry, inter alia, the detection and analysis of …

Five years of scanning electrochemical cell microscopy (SECCM): new insights and innovations

LF Gaudin, IR Wright, TR Harris-Lee, G Jayamaha… - Nanoscale, 2024 - pubs.rsc.org
Scanning electrochemical cell microscopy (SECCM) is a nanopipette-based technique
which enables measurement of localised electrochemistry. SECCM has found use in a wide …

Estimating pitting descriptors of 316 L stainless steel by machine learning and statistical analysis

LB Coelho, D Torres, V Vangrunderbeek… - NPJ Materials …, 2023 - nature.com
A hybrid rule-based/ML approach using linear regression and artificial neural networks
(ANNs) determined pitting corrosion descriptors from high-throughput data obtained with …

Evaluating analytical expressions for scanning electrochemical cell microscopy (SECCM)

KL Anderson, MA Edwards - Analytical Chemistry, 2023 - ACS Publications
Scanning electrochemical cell microscopy (SECCM) maps the electrochemical activity of a
surface with nanoscale resolution using an electrolyte-filled nanopipette. The meniscus at …

A microscopic view on the electrochemical deposition and dissolution of Au with scanning electrochemical cell microscopy–Part I

M Bernal, D Torres, SS Parapari, M Čeh, KŽ Rožman… - Electrochimica …, 2023 - Elsevier
The nucleation and dissolution of gold nanoparticles (NPs) on a glassy carbon substrate
have been studied with a local electrochemical approach based on Scanning …

Revealing the Heterogeneous Bubble Nucleation at Individual Silica Nanoparticles

B Xu, X Meng, J Huang, Y Shan, D Qiu… - Analytical …, 2024 - ACS Publications
Deep understanding of the bubble nucleation process is universally important in systems,
from chemical engineering to materials. However, due to its nanoscale and transient nature …

Controlling nucleation sites for metal oxide film growth on glassy carbon via electrochemical preoxidation

DP Leimkuhl, CL Donley… - ACS Applied Materials & …, 2024 - ACS Publications
Coating electrode materials with metal oxide thin films can improve the performance of
electrocatalysts and charge storage materials. Atomic layer deposition (ALD) enables the …

Correlation function analysis of electrodeposition kinetics and evolving microstructure

JM Rickman, K Barmak, Y Sun, G Zangari - Electrochimica Acta, 2023 - Elsevier
We model electrodeposition using a formalism developed to describe nucleation and growth
processes. In particular, we calculate non-equilibrium, equal-time correlation functions that …

Site-Specific Stochastic Rates and Energetics of Ag Nucleation on Highly Ordered Pyrolytic Graphite

IE Mondaca-Medina, H Ren - ACS nano, 2024 - ACS Publications
Nucleation is a fundamentally important step in electrochemical phase transition reactions,
eg, in electrodeposition, which is pertinent for emerging battery technology, nanoparticle …

Deciphering Spatially‐Resolved Electrochemical Nucleation and Growth Kinetics by Correlative Multimicroscopy

D Torres, M Bernal, J Ustarroz - Small Methods, 2024 - Wiley Online Library
The study employs a multimicroscopy approach, combining Scanning Electrochemical Cell
Microscopy (SECCM) and Field Emission Scanning Electron Microscopy (FESEM), to …