Enantioenriched helicenes and helicenoids containing main-group elements (B, Si, N, P)
K Dhbaibi, L Favereau, J Crassous - Chemical reviews, 2019 - ACS Publications
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …
group elements. Enantioenriched helicenic derivatives containing main-group elements B …
Molecular chirality at surfaces
KH Ernst - physica status solidi (b), 2012 - Wiley Online Library
With the adsorption of larger molecules being increasingly tackled by surface scientists, the
aspect of chirality often plays a role. This paper gives a topical review of molecular chirality …
aspect of chirality often plays a role. This paper gives a topical review of molecular chirality …
Benzo‐Fused Double [7] Carbohelicene: Synthesis, Structures, and Physicochemical Properties
Abstract A benzo‐fused double [7] carbohelicene (D7H) was synthesized through a
regioselective cyclodehydrogenation of a tetranaphthyl‐p‐terphenyl‐based precursor. The …
regioselective cyclodehydrogenation of a tetranaphthyl‐p‐terphenyl‐based precursor. The …
Controlling anisotropic properties by manipulating the orientation of chiral small molecules
Chiral π-conjugated molecules bring new functionality to technological applications and
represent an exciting, rapidly expanding area of research. Their functional properties, such …
represent an exciting, rapidly expanding area of research. Their functional properties, such …
Emergent properties of an organic semiconductor driven by its molecular chirality
Chiral molecules exist as pairs of nonsuperimposable mirror images; a fundamental
symmetry property vastly underexplored in organic electronic devices. Here, we show that …
symmetry property vastly underexplored in organic electronic devices. Here, we show that …
From helical to planar chirality by on-surface chemistry
The chirality of molecular structures is paramount in many phenomena, including
enantioselective reactions, molecular self-assembly, biological processes and light or …
enantioselective reactions, molecular self-assembly, biological processes and light or …
Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces
S Dutta, AJ Gellman - Chemical Society Reviews, 2017 - pubs.rsc.org
Research on surface chirality is motivated by the need to develop functional chiral surfaces
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …
Helicene quinones: redox-triggered chiroptical switching and chiral recognition of the semiquinone radical anion lithium salt by electron nuclear double resonance …
D Schweinfurth, M Zalibera, M Kathan… - Journal of the …, 2014 - ACS Publications
We present the synthesis and characterization of enantiomerically pure [6] helicene o-
quinones (P)-(+)-1 and (M)-(−)-1 and their application to chiroptical switching and chiral …
quinones (P)-(+)-1 and (M)-(−)-1 and their application to chiroptical switching and chiral …
Stereochemical recognition of helicenes on metal surfaces
KH Ernst - Accounts of chemical research, 2016 - ACS Publications
Conspectus The chiral recognition among biomolecules is fundamentally important for many
processes of life, including the stereochemistry of evolution. Of special interest is chiral …
processes of life, including the stereochemistry of evolution. Of special interest is chiral …
Water‐soluble nanoparticles with twisted double [7] carbohelicene for lysosome‐targeted cancer photodynamic therapy
Helicene‐based therapeutic agents for organelle‐targeted photodynamic therapy (PDT)
involving both type I and II are challenging and still underexplored. Herein, water‐soluble …
involving both type I and II are challenging and still underexplored. Herein, water‐soluble …