Microbial host engineering for sustainable isobutanol production from renewable resources

S Nawab, YF Zhang, MW Ullah, AF Lodhi… - Applied Microbiology …, 2024 - Springer
Due to the limited resources and environmental problems associated with fossil fuels, there
is a growing interest in utilizing renewable resources for the production of biofuels through …

Structural crystal engineering for energy: Unleashing the potential of metal-organic frameworks for photocatalytic reduction of carbon dioxide

S Subbareddy, SA Shivamurthy, SB Ravikumar… - Materials Today …, 2024 - Elsevier
Metal-organic frameworks (MOFs) are unique materials with unparalleled potential in
various domains ranging from catalysis to gas storage. The captivating synergy between …

Direct biomass valorisation to γ-valerolactone by Ru-PNP catalysed hydrogenation in acid

S Koranchalil, M Nielsen - Ees Catalysis, 2024 - pubs.rsc.org
Converting carbohydrate-rich biomass waste directly to γ-valerolactone (GVL) is highly
attractive but challenging owing to the inert nature and high complexity of biomass …

Base-free, acceptorless dehydrogenative coupling of ethanol to ethyl acetate with PNP complexes

Z Ni, R Padilla, R Pramanick, MSB Jørgensen… - Dalton …, 2023 - pubs.rsc.org
A base-free, acceptorless dehydrogenative coupling of ethanol to ethyl acetate is presented.
By using the pincer complex (PhPNP) RuH (BH4)(CO)(0.25 mol%) in the presence of m …

Homogeneous Catalyzed Direct Conversion of Furfural to Gamma‐Valerolactone

S Koranchalil, D Lobo Justo Pinheiro, R Padilla… - …, 2024 - Wiley Online Library
Herein, we report the direct conversion of biomass‐derived furfural to γ‐valerolactone (GVL)
in a one‐pot system, using the combination of Ru‐MACHO‐BH and a Brønsted acid …

Mild synthesis of C6+ higher alcohols from aqueous ethanol upgrading over Ni@ MB catalyst derived from melt-blown cloth

Q Zhang, Y Cen, B Chen, J Li, X Zheng, X Wu… - Chemical Engineering …, 2024 - Elsevier
Direct synthesis of alternative higher alcohols from aqueous bio-ethanol has received
increasing attention because of its promising application in value-add fine chemicals and …

Backbone-functionalised ruthenium diphosphine complexes for catalytic upgrading of ethanol and methanol to iso-butanol

FJ Sama, RA Doyle, BM Kariuki, NE Pridmore… - Dalton …, 2024 - pubs.rsc.org
Efficient catalysts for Guerbet-type ethanol/methanol upgrading to iso-butanol have been
developed via Michael addition of a variety of amines to ruthenium-coordinated dppen (1, 1 …

Morphology based catalytic oxidation of phenylpropyne into 1, 2-diketones, aldehyde and acid using Cu (II) complex

P Kaushik, N Malik, P Tevatia… - Applied …, 2023 - systems.enpress-publisher.com
Abstract Aldehyde, 1, 2-diketones, and acid were prepared by copper-catalyzed oxidation of
phenyl propyne, using t-BuOOH as the oxidant, heterogeneously. Aldehyde is formed as a …

Direct valorization of biomass waste to gamma-valerolactone

S Koranchalil, M Nielsen - 2023 - chemrxiv.org
Biomass is the only renewable hydrocarbon resource on Earth and therefore plays an
essential role in a future sustainable society. Nevertheless, biomass is underutilized for …

POP Pincer Complexes of Ruthenium and Manganese for Small Molecule Transformations

AT Nikol - 2023 - orbit.dtu.dk
This thesis summarizes and discusses the results of six separate projects within the PhD
studies and totals eight chapters, followed by ten appendices containing general …