Transition-metal-catalyzed intramolecular nucleophilic addition of carbonyl groups to alkynes
L Chen, K Chen, S Zhu - Chem, 2018 - cell.com
Compounds consisting of a carbonyl group and an alkyne group, especially enynals and
enynones, are versatile and powerful building blocks for generating structurally diverse …
enynones, are versatile and powerful building blocks for generating structurally diverse …
Donor-and acceptor-enynals/enynones
L Chen, Z Liu, S Zhu - Organic & Biomolecular Chemistry, 2018 - pubs.rsc.org
Enynals and enynones have emerged as focal substrates in organic synthesis in view of
their structure diversity, high reactivity and intermediate variety. Transition metal-or Lewis …
their structure diversity, high reactivity and intermediate variety. Transition metal-or Lewis …
Formation of C(sp2)Boronate Esters by Borylative Cyclization of Alkynes Using BCl3
AJ Warner, JR Lawson, V Fasano… - Angewandte …, 2015 - Wiley Online Library
BCl3 is an inexpensive electrophile which induces the borylative cyclization of a wide range
of substituted alkynes to regioselectively form polycycles containing synthetically versatile C …
of substituted alkynes to regioselectively form polycycles containing synthetically versatile C …
[HTML][HTML] Isoquinolone syntheses by annulation protocols
R Hua - Catalysts, 2021 - mdpi.com
Isoquinolones (isoquinolin-1 (2 H)-ones) are one of the important nitrogen-heterocyclic
compounds having versatile biological and physiological activities, and their synthetic …
compounds having versatile biological and physiological activities, and their synthetic …
Gold-catalyzed synthesis of tetrahydrocarbazole derivatives through an intermolecular cycloaddition of vinyl indoles and N-allenamides
V Pirovano, L Decataldo, E Rossi… - Chemical …, 2013 - pubs.rsc.org
Gold-catalyzed synthesis of tetrahydrocarbazole derivatives through an intermolecular
cycloaddition of vinyl indoles and N -allenamides - Chemical Communications (RSC Publishing) …
cycloaddition of vinyl indoles and N -allenamides - Chemical Communications (RSC Publishing) …
Ligand-controlled chemoselectivity in gold-catalyzed cascade cyclization of 1, 4-diene-tethered 2-alkynylbenzaldehydes
J Chen, R Hu, Q Bao, D Shang, L Yu… - Organic Chemistry …, 2022 - pubs.rsc.org
A method to chemo-and stereoselectively assemble polycyclic bridged pyrrolidines and
azepines which relies on the gold (I)-catalyzed cascade annulation of skipped 1, 4-diene …
azepines which relies on the gold (I)-catalyzed cascade annulation of skipped 1, 4-diene …
Gold-catalyzed cycloisomerization and Diels–Alder reaction of 1, 6-diyne esters with alkenes and diazenes to hydronaphthalenes and-cinnolines
A method for the efficient preparation of hydronaphthalene and-cinnoline derivatives by Au
(I)-catalyzed cycloisomerzation of 1, 6-diyne esters followed by a Diels–Alder reaction with …
(I)-catalyzed cycloisomerzation of 1, 6-diyne esters followed by a Diels–Alder reaction with …
Borylative cyclization reactions
E Buñuel, DJ Cárdenas - European Journal of Organic …, 2016 - Wiley Online Library
Borylative cyclizations constitute a family of important cascade reactions for the formation of
carbo‐and heterocycles containing boryl substituents. These compounds are formed from a …
carbo‐and heterocycles containing boryl substituents. These compounds are formed from a …
Gold-Catalyzed Oxidative Cyclizations of {o-(Alkynyl)phenyl propargyl} Silyl Ether Derivatives Involving 1,2-Enynyl Migration: Synthesis of Functionalized 1H-Isochromenes and …
A new and convenient strategy for the synthesis of functionalized 1 H-isochromene and 2 H-
pyran derivatives based on gold-catalyzed oxidative cyclizations of o-(alkynyl) phenyl …
pyran derivatives based on gold-catalyzed oxidative cyclizations of o-(alkynyl) phenyl …
Organocatalytic Asymmetric Multicomponent Cascade Reaction for the Synthesis of Contiguously Substituted Tetrahydronaphthols
Isobenzopyrylium ions are unique, highly reactive, aromatic intermediates which are largely
unexplored in asymmetric catalysis despite their high potential synthetic utility. In this study …
unexplored in asymmetric catalysis despite their high potential synthetic utility. In this study …