Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes

Z Liu, SKM Nalluri, JF Stoddart - Chemical Society Reviews, 2017 - pubs.rsc.org
Macrocycles are molecular entities that display a combination of molecular recognition and
complexation properties with vital implications for host–guest/supramolecular chemistry …

Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry

T Ogoshi, T Yamagishi, Y Nakamoto - Chemical reviews, 2016 - ACS Publications
In 2008, we reported a new class of pillar-shaped macrocyclic hosts, known as “pillar [n]
arenes”. Today, pillar [n] arenes are recognized as key players in supramolecular chemistry …

[HTML][HTML] Biomedical applications of supramolecular systems based on host–guest interactions

X Ma, Y Zhao - Chemical reviews, 2015 - ACS Publications
The development of supramolecular chemistry dates back to 1987 when Lehn, Cram, and
Pedersen won the Nobel Prize on account of their leading discoveries in the host–guest …

Pillararene-based molecular-scale porous materials

MH Li, XY Lou, YW Yang - Chemical Communications, 2021 - pubs.rsc.org
This review discusses the design and syntheses of molecular-scale pillar [n] arene-based
porous materials with promising applications and summarises the development of using …

Biological and related applications of pillar [n] arenes

CW Sathiyajith, RR Shaikh, Q Han, Y Zhang… - Chemical …, 2017 - pubs.rsc.org
Pillar [n] arenes are a new class of synthetic supramolecular macrocycles streamlined by
their particular pillar-shaped architecture which consists of an electron-rich cavity and two …

Chiral pillar [n] arenes: Conformation inversion, material preparation and applications

C Shi, H Li, X Shi, L Zhao, H Qiu - Chinese Chemical Letters, 2022 - Elsevier
Chiral pillar [n] arenes have shown great research value and application prospect in
construction of chiral materials and chiral applications, due to their inherent planar chiral …

Macrocycles as drug-enhancing excipients in pharmaceutical formulations

A Gu, NJ Wheate - Journal of Inclusion Phenomena and Macrocyclic …, 2021 - Springer
The macrocycle families: cucurbit [n] urils, n-cyclodextrins, calix [n] arenes, and pillar [n]
arenes (where n represents the number of subunits in each homologue) have shown …

Per-Arylation of Pillar[n]arenes: An Effective Tool to Modify the Properties of Macrocycles

K Kato, T Kaneda, S Ohtani… - Journal of the American …, 2023 - ACS Publications
Installation of various substituents is a reliable and versatile way to alter the properties of
macrocyclic molecules, but high-yield and controlled methods are not always available …

Discrete chiral organic nanotubes by stacking pillar [5] arenes using covalent linkages

TH Shi, S Fa, Y Nagata, K Wada, S Ohtani… - Cell Reports Physical …, 2022 - cell.com
Owing to their unique one-dimensional hollow structures, organic nanotubes have been
widely explored in recent years. Covalent organic nanotubes (CONs) can be prepared by …

Functionalization at will of rim-differentiated pillar [5] arenes

P Demay-Drouhard, K Du, K Samanta, X Wan… - Organic …, 2019 - ACS Publications
The development of an efficient synthetic route toward rim-differentiated C 5-symmetric pillar
[5] arenes (P [5] s), whose two rims are decorated with different chemical functionalities …