One-dimensional coordination polymers: complexity and diversity in structures, properties, and applications

WL Leong, JJ Vittal - Chemical reviews, 2011 - ACS Publications
One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties,
and Applications | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log …

Control of charge transfer in donor/acceptor metal–organic frameworks

H Miyasaka - Accounts of chemical research, 2013 - ACS Publications
Charge transfer (CT) of D0A0↔ Dδ+ Aδ− not only involves an electron transfer from D to A,
but also generates a new spin set of S= 1/2 spins with an exchange interaction. Therefore …

Control of Charge Transfer in a Series of Ru2II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magnetic …

H Miyasaka, N Motokawa, S Matsunaga… - Journal of the …, 2010 - ACS Publications
The isostructural series of two-dimensional (2-D) fishnet-type network compounds,[{Ru2
(O2CCF3) 4} 2 (TCNQR x)]· n (solv)(R x= H4, 1; Br2, 2; Cl2, 3; F2, 4; F4, 5), has been …

Charge manipulation in metal–organic frameworks: toward designer functional molecular materials

H Miyasaka - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Multi-dimensional coordination frameworks whose charge states are controllable by the
sophisticated chemical modification of the components or by the application of stimuli are …

An Electron‐Transfer Ferromagnet with Tc=107 K Based on a Three‐Dimensional [Ru2]2/TCNQ System

N Motokawa, H Miyasaka, M Yamashita… - Angewandte Chemie …, 2008 - Wiley Online Library
The design of dπ–pπ molecular systems with efficient electronic communication is a long-
standing goal in the field of inorganic chemistry. Guiding principles for this research are …

Tetracyanoquinodimethane doped copper-organic framework electrode with excellent electrochemical performance for energy storage applications

S Sundriyal, V Shrivastav, SK Bhardwaj, S Mishra… - Electrochimica …, 2021 - Elsevier
Metal-organic frameworks (MOFs) are emerging as potential electrode materials for next-
generation energy storage devices. Cu 3 (BTC) 2 (BTC= benzene tricarboxylate), also …

Metal–Organic Frameworks Derived from Calcium and Strontium Complexes of a Redox-Active Ligand

NL Bazyakina, VM Makarov, SY Ketkov… - Inorganic …, 2021 - ACS Publications
The reactions of monomeric [(dpp-Bian) M (thf) 4](M= Ca (1a), Sr (1b); dpp-Bian= 1, 2-bis [(2,
6-diisopropylphenyl) imino] acenaphthene) with 4, 4′-bipyridyl (4, 4′-bipy) proceed with …

Tuning of the ionization potential of paddlewheel diruthenium (II, II) complexes with fluorine atoms on the benzoate ligands

H Miyasaka, N Motokawa, R Atsuumi, H Kamo… - Dalton …, 2011 - pubs.rsc.org
A series of paddlewheel diruthenium (II, II) complexes with various fluorine-substituted
benzoate ligands were isolated as THF adducts and structurally characterized:[Ru2 …

Charge-transfer two-dimensional layers constructed from a 2: 1 assembly of paddlewheel diruthenium (II, II) complexes and bis [1, 2, 5] …

N Motokawa, T Oyama, S Matsunaga, H Miyasaka… - …, 2009 - pubs.rsc.org
Two new charge-transfer compounds,[{Ru2 (O2CPh-xF) 4} 2 (BTDA-TCNQ)]· n (solv)(xF-
PhCO2−= x-fluorobenzoate; x= o-, 4; p-, 5; BTDA-TCNQ= bis [1, 2, 5] …

A three-dimensional network of two-electron-transferred [Ru 2] 2 TCNQ exhibiting anomalous conductance due to charge fluctuations

H Miyasaka, T Morita, M Yamashita - Chemical Communications, 2011 - pubs.rsc.org
A new D2A-type charge-transfer three-dimensional network with a charge distribution of
[{Ru2} δ+–(BTDA-TCNQ2δ−)–{Ru2} δ+] where δ≈ 1, which exhibits a sudden decrease in …