Metal-catalyzed approaches toward the oxindole core
Conspectus The oxindole scaffold is a privileged structural motif that is found in a variety of
bioactive targets and natural products. Moreover, derivatives of the oxindole structure are …
bioactive targets and natural products. Moreover, derivatives of the oxindole structure are …
Recent advances in fixation of CO2 into organic carbamates through multicomponent reaction strategies
L Wang, C Qi, W Xiong, H Jiang - Chinese Journal of Catalysis, 2022 - Elsevier
Carbon dioxide (CO 2) is the main greenhouse gas and also an ideal C1 feedstock in
organic synthesis because it is abundant, non-toxic, nonflammable, and renewable. The …
organic synthesis because it is abundant, non-toxic, nonflammable, and renewable. The …
Nickel‐Catalyzed Asymmetric Reductive Carbo‐Carboxylation of Alkenes with CO2
XW Chen, JP Yue, K Wang, YY Gui, YN Niu… - Angewandte …, 2021 - Wiley Online Library
Reductive carboxylation of organo (pseudo) halides with CO2 is a powerful method to
provide carboxylic acids quickly. Notably, the catalytic reductive carbo‐carboxylation of …
provide carboxylic acids quickly. Notably, the catalytic reductive carbo‐carboxylation of …
P, N Ligand in Ni-Catalyzed Cross-Coupling Reactions: A Promising Tool for π-Functionalization
J Bae, EJ Cho - ACS Catalysis, 2023 - ACS Publications
Bidentate P, N ligands, integrating phosphine and nitrogen donors, are highlighted for their
versatile characteristics, offering both electronic and steric tunability. Their hemilabile nature …
versatile characteristics, offering both electronic and steric tunability. Their hemilabile nature …
Quinim: a new ligand scaffold enables nickel-catalyzed enantioselective synthesis of α-alkylated γ-lactam
X Wu, J Qu, Y Chen - Journal of the American Chemical Society, 2020 - ACS Publications
Herein, we report a nickel-catalyzed reductive cross-coupling reaction of easily accessible 3-
butenyl carbamoyl chloride with primary alkyl iodide to access the chiral α-alkylated …
butenyl carbamoyl chloride with primary alkyl iodide to access the chiral α-alkylated …
An insight into the advanced synthetic recipes to access ubiquitous indole heterocycles
Indoles are amongst the most essential class of heteroaromatics in organic chemistry, being
commonly found in biologically active natural products. Indole and its derivatives have …
commonly found in biologically active natural products. Indole and its derivatives have …
2-Oxindole and related heterocycles: synthetic methodologies for their natural products and related derivatives
Natural goods, medications, and pharmaceutically active substances all contain substituted
oxindoles. Generally, the C-3 stereocenter of the substituents of oxindoles and their absolute …
oxindoles. Generally, the C-3 stereocenter of the substituents of oxindoles and their absolute …
Three-component visible-light-induced palladium-catalyzed 1, 2-alkyl carbamoylation/cyanation of alkenes
A mild visible-light-induced Pd-catalyzed one-pot three-component alkyl-carbamoylation
and cyanation of alkenes was developed. This general transformation, which proceeds via …
and cyanation of alkenes was developed. This general transformation, which proceeds via …
Photo‐Excited Nickel‐Catalyzed Silyl‐Radical‐Mediated Direct Activation of Carbamoyl Chlorides To Access (Hetero) aryl Carbamides
Amide bonds connect the amino acids in proteins and exist as a prevalent structural motif in
biomolecules. Herein, we have exploited the concept of cross‐electrophile coupling by …
biomolecules. Herein, we have exploited the concept of cross‐electrophile coupling by …
Carbamoyl fluoride-enabled enantioselective Ni-catalyzed carbocarbamoylation of unactivated alkenes
Y Li, FP Zhang, RH Wang, SL Qi… - Journal of the American …, 2020 - ACS Publications
Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of
Unactivated Alkenes | Journal of the American Chemical Society ACS ACS Publications …
Unactivated Alkenes | Journal of the American Chemical Society ACS ACS Publications …