Reported herein is an unprecedented synthesis of isoxazolines and oxazines through
electrochemical intermolecular annulation of alkenes with tert-butyl nitrite, in which diazo …

Polynuclear metal hydride clusters play important roles in various catalytic processes, with
most of the reported polynuclear metal hydride clusters adopting a polyhedral three …

This is a review of papers published in the year 2018 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …

A computational study on amino-and nitro-substituted penta-and heptafulvenes reveals the
interplay between the aromaticity and the substituent effect (SE). Ring substitution alone has …

The substitution of the chlorido ligand of bis (η5: η1-(di-p-tolyl)-pentafulvene) niobium
chloride by reaction with (trimethylsilyl) methyllithium is followed by α-C–H bond activation …

Abstract Bis (η5: η1‐(di‐para‐tolyl) pentafulvene) niobium chloride (1) reacts with methyl
lithium via salt metathesis to the methylated bis (pentafulvene) niobium complex 2, and with …

The π–η5: σ–η1 coordination mode of early transition metal pentafulvene ligands yields a
strongly nucleophilic exocyclic carbon atom (Cexo). The substitution of the chlorido ligand of …

A series of titanium amidinato complexes were synthesized by stoichiometric insertion
reactions of carbodiimides into bis (π-η5: σ-η1-pentafulvene) titanium complexes. NMR …

A flexible [PNP] ligand (forming six-membered chelates upon coordination) was employed
for the synthesis of niobium (IV) and tantalum (IV) complexes. Starting from the protioligand …

The benzene ligand at CpV (η6− C6H6)(1) is exchanged for pentafulvenes. Using sterically
demanding pentafulvenes gives a clean exchange reaction, yielding vanadium …