In the last 30 years, since the discovery that vanadium is a cofactor found in certain enzymes
of tunicates and possibly in mammals, different vanadium-based drugs have been …

Different aspects of the coordination chemistry of oxovanadium (IV) and oxovanadium (V),
relevant to the bioinorganic chemistry of vanadium, are presented. Some of the investigated …

Although dogma states that vanadate is readily reduced by glutathione, cysteine, and other
thiols, there are several examples documenting that vanadium (V)− sulfur complexes can …

Different aspects of the chemistry and biochemistry of vanadium are analyzed in this review.
The preparation and characterization of oxovanadates and polyoxovanadates, including …

The crystallographic structures of both the vanadium chloroperoxidase and
bromoperoxidase enzymes have been determined with either vanadium or phosphate …

Circular dichroism (CD) spectroscopy is widely used to study biological systems and
nonbiological systems, being an invaluable tool in inorganic chemistry, particularly in …

The pyrimidinones mhcpe, 2-methyl-3H-5-hydroxy-6-carboxy-4-pyrimidinone ethyl ester
(mhcpe, 1), 2, 3-dimethyl-5-benzyloxy-6-carboxy-4-pyrimidinone ethyl ester (dbcpe, 2) and …

In this work the binding of V IV O 2+ and V IV O-complexes to serum albumins {human
serum albumin (HSA), bovine serum albumin (BSA) and porcine serum albumin (PSA)} are …

The oxovanadium cation, V02+, has been successfully employed as a spin probe1 in
electron—nuclear double resonance (ENDOR) 2, 3 and electron spin echo envelope …

The equilibria of the complexation processes of V3+ ion with l-phenylalanine, l-tyrosine, l-
tryptophan and l-proline in aqueous solution were studied by potentiometric and …