Recent progress and strategic perspectives of inorganic solid electrolytes: fundamentals, modifications, and applications in sodium metal batteries

J Huang, K Wu, G Xu, M Wu, S Dou, C Wu - Chemical Society Reviews, 2023 - pubs.rsc.org
Solid-state electrolytes (SEs) have attracted overwhelming attention as a promising
alternative to traditional organic liquid electrolytes (OLEs) for high-energy-density sodium …

Exploiting the paddle-wheel mechanism for the design of fast ion conductors

Z Zhang, LF Nazar - Nature Reviews Materials, 2022 - nature.com
As an indispensable component in solid-state devices, superionic conductors can exhibit
liquid-like and exceptionally high alkali cation conductivity in their crystalline lattices. A …

Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries

X Feng, H Fang, N Wu, P Liu, P Jena, J Nanda, D Mitlin - Joule, 2022 - cell.com
The design of solid-state electrolyte (SSE) entails controlling not only its bulk structure but
also the internal (eg, grain boundary and pore) and heterophase (eg, anode-SSE reaction …

New family of argyrodite thioantimonate lithium superionic conductors

L Zhou, A Assoud, Q Zhang, X Wu… - Journal of the American …, 2019 - ACS Publications
We report on a new family of argyrodite lithium superionic conductors, as solid solutions
Li6+ x M x Sb1–x S5I (M= Si, Ge, Sn), that exhibit superionic conductivity. These represent …

A complex hydride lithium superionic conductor for high-energy-density all-solid-state lithium metal batteries

S Kim, H Oguchi, N Toyama, T Sato, S Takagi… - Nature …, 2019 - nature.com
All-solid-state batteries incorporating lithium metal anode have the potential to address the
energy density issues of conventional lithium-ion batteries that use flammable organic liquid …

Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage

SP Fisher, AW Tomich, SO Lovera… - Chemical …, 2019 - ACS Publications
Classically closo-carborane anions, particularly [HCB11H11]− and [HCB9H9]−, and their
derivatives have primarily been used as weakly coordinating anions to isolate reactive …

Li10GeP2S12‐Type Superionic Conductors: Synthesis, Structure, and Ionic Transportation

Y Kato, S Hori, R Kanno - Advanced Energy Materials, 2020 - Wiley Online Library
Ever since the first report on Li10GeP2S12 (LGPS) in 2011, its unique structure and
exceptionally high lithium conductivity (> 1× 10− 2 S cm− 1) have attracted extensive …

Materials design of ionic conductors for solid state batteries

S Ohno, A Banik, GF Dewald, MA Kraft… - Progress in …, 2020 - iopscience.iop.org
All-solid-state batteries, employing inorganic ion conductors as electrolytes, can surpass the
current Li-ion technology in terms of energy density, battery safety, specific power, as well as …

Classical and emerging characterization techniques for investigation of ion transport mechanisms in crystalline fast ionic conductors

Y Gao, AM Nolan, P Du, Y Wu, C Yang, Q Chen… - Chemical …, 2020 - ACS Publications
Ion transport in crystalline fast ionic conductors is a complex physical phenomenon. Certain
ionic species (eg, Ag+, Cu+, Li+, F–, O2–, H+) in a solid crystalline framework can move as …

Progress in three-dimensional aromatic-like closo-dodecaborate

X Zhao, Z Yang, H Chen, Z Wang, X Zhou… - Coordination Chemistry …, 2021 - Elsevier
The continuous discovery and derivatization of members of the closed borane family
indicate that boron chemistry is about to embark on a development trajectory similar to that …